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Radically promoted formation of a molecular lasso

Two potential viologen-based molecular lasso precursors—both composed of a 4,4′-bipyridinium (BIPY(2+)) unit as part of a rope appended to a cyclobis(paraquat-p-phenylene) (CBPQT(4+)) loop—that have been designed to mimic the threading/unthreading motion of lasso peptides, have been synthesised and...

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Detalles Bibliográficos
Autores principales: Wang, Yuping, Sun, Junling, Liu, Zhichang, Nassar, Majed S., Botros, Youssry Y., Stoddart, J. Fraser
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5431688/
https://www.ncbi.nlm.nih.gov/pubmed/28553488
http://dx.doi.org/10.1039/c6sc05035b