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Synthesis of D-manno-heptulose via a cascade aldol/hemiketalization reaction
A [4 + 3] synthesis of D-manno-heptulose is described. The cascade aldol/hemiketalization reaction of a C(4) aldehyde with a C(3) ketone provides the differentially protected ketoheptose building block, which can be further reacted to furnish target D-manno-heptulose.
Autores principales: | Chen, Yan, Wang, Xiaoman, Wang, Junchang, Yang, You |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433184/ https://www.ncbi.nlm.nih.gov/pubmed/28546836 http://dx.doi.org/10.3762/bjoc.13.79 |
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