Cargando…

Intra- versus intermolecular electron transfer in radical nucleophilic aromatic substitution of dihalo(hetero)arenes – a tool for estimating π-conjugation in aromatic systems

In this paper, the application of the double radical nucleophilic aromatic substitution (S(RN)1) in various dihalogenated, mostly diiodinated, π-conjugated systems as a tool for qualitatively estimating their π-conjugation is described. This approach uses electron delocalisation as a measure of π-co...

Descripción completa

Detalles Bibliográficos
Autores principales: Janhsen, B., Daniliuc, C. G., Studer, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5436300/
https://www.ncbi.nlm.nih.gov/pubmed/28580099
http://dx.doi.org/10.1039/c7sc00100b