Hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions

Hydrolysis data for Bis(3-(3,4-dicyanophenoxy)phenyl) phenyl phosphate and Bis(3-(3,4-dicyanophenoxy)phenyl) phenylphosphonate under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the reactions products are given. Pseudo-first...

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Autores principales: Belsky, Kirill S., Sulimov, Artem V., Bulgakov, Boris A., Babkin, Alexandr V., Kepman, Alexey V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2017
Materias:
Data Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5440757/
https://www.ncbi.nlm.nih.gov/pubmed/28560276
http://dx.doi.org/10.1016/j.dib.2017.05.015
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author Belsky, Kirill S.
Sulimov, Artem V.
Bulgakov, Boris A.
Babkin, Alexandr V.
Kepman, Alexey V.
author_facet Belsky, Kirill S.
Sulimov, Artem V.
Bulgakov, Boris A.
Babkin, Alexandr V.
Kepman, Alexey V.
author_sort Belsky, Kirill S.
collection PubMed
description Hydrolysis data for Bis(3-(3,4-dicyanophenoxy)phenyl) phenyl phosphate and Bis(3-(3,4-dicyanophenoxy)phenyl) phenylphosphonate under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the reactions products are given. Pseudo-first order rate constants are determined for both substrates at 25, 50 and 80 °C. Activation parameters were calculated from Arrhenius equation.
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spelling pubmed-54407572017-05-30 Hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions Belsky, Kirill S. Sulimov, Artem V. Bulgakov, Boris A. Babkin, Alexandr V. Kepman, Alexey V. Data Brief Data Article Hydrolysis data for Bis(3-(3,4-dicyanophenoxy)phenyl) phenyl phosphate and Bis(3-(3,4-dicyanophenoxy)phenyl) phenylphosphonate under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the reactions products are given. Pseudo-first order rate constants are determined for both substrates at 25, 50 and 80 °C. Activation parameters were calculated from Arrhenius equation. Elsevier 2017-05-10 /pmc/articles/PMC5440757/ /pubmed/28560276 http://dx.doi.org/10.1016/j.dib.2017.05.015 Text en © 2017 Published by Elsevier Inc. http://creativecommons.org/licenses/by/4.0/ This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Data Article
Belsky, Kirill S.
Sulimov, Artem V.
Bulgakov, Boris A.
Babkin, Alexandr V.
Kepman, Alexey V.
Hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions
title Hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions
title_full Hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions
title_fullStr Hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions
title_full_unstemmed Hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions
title_short Hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions
title_sort hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions
topic Data Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5440757/
https://www.ncbi.nlm.nih.gov/pubmed/28560276
http://dx.doi.org/10.1016/j.dib.2017.05.015
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