The Effect of Sulphate Anions on the Ultrafine Titania Nucleation

The phenomenological model of sulphate anions effect on the nanodispersed titania synthesis during hydrolysis of titanium tetrachloride was studied. It was proposed that both chelating and bridging bidentate complexes formation between sulphate anions and octahedrally coordinated [Ti(OH)(h)(OH(2))(6...

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Autores principales: Kotsyubynsky, Volodymyr O., Myronyuk, Ivan F., Chelyadyn, Volodymyr L., Hrubiak, Andriy B., Moklyak, Volodymyr V., Fedorchenko, Sofia V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2017
Materias:
Nano Express
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5442038/
https://www.ncbi.nlm.nih.gov/pubmed/28545263
http://dx.doi.org/10.1186/s11671-017-2144-3
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author Kotsyubynsky, Volodymyr O.
Myronyuk, Ivan F.
Chelyadyn, Volodymyr L.
Hrubiak, Andriy B.
Moklyak, Volodymyr V.
Fedorchenko, Sofia V.
author_facet Kotsyubynsky, Volodymyr O.
Myronyuk, Ivan F.
Chelyadyn, Volodymyr L.
Hrubiak, Andriy B.
Moklyak, Volodymyr V.
Fedorchenko, Sofia V.
author_sort Kotsyubynsky, Volodymyr O.
collection PubMed
description The phenomenological model of sulphate anions effect on the nanodispersed titania synthesis during hydrolysis of titanium tetrachloride was studied. It was proposed that both chelating and bridging bidentate complexes formation between sulphate anions and octahedrally coordinated [Ti(OH)(h)(OH(2))(6−h)]((4−h)+) mononers is the determinative factor for anatase phase nucleation.
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spelling pubmed-54420382017-06-09 The Effect of Sulphate Anions on the Ultrafine Titania Nucleation Kotsyubynsky, Volodymyr O. Myronyuk, Ivan F. Chelyadyn, Volodymyr L. Hrubiak, Andriy B. Moklyak, Volodymyr V. Fedorchenko, Sofia V. Nanoscale Res Lett Nano Express The phenomenological model of sulphate anions effect on the nanodispersed titania synthesis during hydrolysis of titanium tetrachloride was studied. It was proposed that both chelating and bridging bidentate complexes formation between sulphate anions and octahedrally coordinated [Ti(OH)(h)(OH(2))(6−h)]((4−h)+) mononers is the determinative factor for anatase phase nucleation. Springer US 2017-05-23 /pmc/articles/PMC5442038/ /pubmed/28545263 http://dx.doi.org/10.1186/s11671-017-2144-3 Text en © The Author(s). 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Kotsyubynsky, Volodymyr O.
Myronyuk, Ivan F.
Chelyadyn, Volodymyr L.
Hrubiak, Andriy B.
Moklyak, Volodymyr V.
Fedorchenko, Sofia V.
The Effect of Sulphate Anions on the Ultrafine Titania Nucleation
title The Effect of Sulphate Anions on the Ultrafine Titania Nucleation
title_full The Effect of Sulphate Anions on the Ultrafine Titania Nucleation
title_fullStr The Effect of Sulphate Anions on the Ultrafine Titania Nucleation
title_full_unstemmed The Effect of Sulphate Anions on the Ultrafine Titania Nucleation
title_short The Effect of Sulphate Anions on the Ultrafine Titania Nucleation
title_sort effect of sulphate anions on the ultrafine titania nucleation
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5442038/
https://www.ncbi.nlm.nih.gov/pubmed/28545263
http://dx.doi.org/10.1186/s11671-017-2144-3
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