Mechanochemical Effects on the Synthesis of Copper Orthophosphate and cyclo-Tetraphosphate Bulks by the Hydrothermal Hot Pressing Method

Copper orthophosphate, Cu(3)(PO(4))(2), and cyclo-tetraphosphates, Cu(2)P(4)O(12), were synthesized using phosphoric acid and basic copper carbonate, and then treated with a planetary mill for up to 360 minutes. The un-milled and milled samples were characterized by X-ray diffraction (XRD) and Fouri...

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Autores principales: Onoda, Hiroaki, Okumoto, Ken-ichi, Nakahira, Atsushi, Tanaka, Isao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5445695/
http://dx.doi.org/10.3390/ma2010001
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author Onoda, Hiroaki
Okumoto, Ken-ichi
Nakahira, Atsushi
Tanaka, Isao
author_facet Onoda, Hiroaki
Okumoto, Ken-ichi
Nakahira, Atsushi
Tanaka, Isao
author_sort Onoda, Hiroaki
collection PubMed
description Copper orthophosphate, Cu(3)(PO(4))(2), and cyclo-tetraphosphates, Cu(2)P(4)O(12), were synthesized using phosphoric acid and basic copper carbonate, and then treated with a planetary mill for up to 360 minutes. The un-milled and milled samples were characterized by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy. SEM images, particle size distribution, specific surface area, UV-Vis reflectance spectra were also used to evaluate the materials. The un-milled and milled materials were used to fabricate copper phosphate bulks by a hydrothermal hot pressing method. The influence of powder condition on the sintering behavior of the copper phosphates was studied.
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spelling pubmed-54456952017-07-28 Mechanochemical Effects on the Synthesis of Copper Orthophosphate and cyclo-Tetraphosphate Bulks by the Hydrothermal Hot Pressing Method Onoda, Hiroaki Okumoto, Ken-ichi Nakahira, Atsushi Tanaka, Isao Materials (Basel) Article Copper orthophosphate, Cu(3)(PO(4))(2), and cyclo-tetraphosphates, Cu(2)P(4)O(12), were synthesized using phosphoric acid and basic copper carbonate, and then treated with a planetary mill for up to 360 minutes. The un-milled and milled samples were characterized by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy. SEM images, particle size distribution, specific surface area, UV-Vis reflectance spectra were also used to evaluate the materials. The un-milled and milled materials were used to fabricate copper phosphate bulks by a hydrothermal hot pressing method. The influence of powder condition on the sintering behavior of the copper phosphates was studied. Molecular Diversity Preservation International 2009-01-09 /pmc/articles/PMC5445695/ http://dx.doi.org/10.3390/ma2010001 Text en © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Onoda, Hiroaki
Okumoto, Ken-ichi
Nakahira, Atsushi
Tanaka, Isao
Mechanochemical Effects on the Synthesis of Copper Orthophosphate and cyclo-Tetraphosphate Bulks by the Hydrothermal Hot Pressing Method
title Mechanochemical Effects on the Synthesis of Copper Orthophosphate and cyclo-Tetraphosphate Bulks by the Hydrothermal Hot Pressing Method
title_full Mechanochemical Effects on the Synthesis of Copper Orthophosphate and cyclo-Tetraphosphate Bulks by the Hydrothermal Hot Pressing Method
title_fullStr Mechanochemical Effects on the Synthesis of Copper Orthophosphate and cyclo-Tetraphosphate Bulks by the Hydrothermal Hot Pressing Method
title_full_unstemmed Mechanochemical Effects on the Synthesis of Copper Orthophosphate and cyclo-Tetraphosphate Bulks by the Hydrothermal Hot Pressing Method
title_short Mechanochemical Effects on the Synthesis of Copper Orthophosphate and cyclo-Tetraphosphate Bulks by the Hydrothermal Hot Pressing Method
title_sort mechanochemical effects on the synthesis of copper orthophosphate and cyclo-tetraphosphate bulks by the hydrothermal hot pressing method
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5445695/
http://dx.doi.org/10.3390/ma2010001
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