Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer

Amorphous Spherical Carbon with Nitrogen (SCN) active carbon has been prepared by carbonization of poly(vinylpyridine-divinylbenzene) (PVPDVB) copolymer. The PVPDVB dehydrogenation copolymer has been quantum chemically (QC) simulated using cluster and periodic models. Scanning electron microscopy (S...

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Autores principales: Khavryuchenko, Volodymyr D., Khavryuchenko, Oleksiy V., Shkilnyy, Andriy I., Stratiichuk, Denys A., Lisnyak, Vladyslav V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5445732/
http://dx.doi.org/10.3390/ma2031239
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author Khavryuchenko, Volodymyr D.
Khavryuchenko, Oleksiy V.
Shkilnyy, Andriy I.
Stratiichuk, Denys A.
Lisnyak, Vladyslav V.
author_facet Khavryuchenko, Volodymyr D.
Khavryuchenko, Oleksiy V.
Shkilnyy, Andriy I.
Stratiichuk, Denys A.
Lisnyak, Vladyslav V.
author_sort Khavryuchenko, Volodymyr D.
collection PubMed
description Amorphous Spherical Carbon with Nitrogen (SCN) active carbon has been prepared by carbonization of poly(vinylpyridine-divinylbenzene) (PVPDVB) copolymer. The PVPDVB dehydrogenation copolymer has been quantum chemically (QC) simulated using cluster and periodic models. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy dispersive X-ray (EDX) studies of the resulting product have conformed the QC computation results. Great structural similarity is found both at the nano- and micro-levels between the N-doped SCN carbon and its pure carbonic SKS analog.
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spelling pubmed-54457322017-07-28 Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer Khavryuchenko, Volodymyr D. Khavryuchenko, Oleksiy V. Shkilnyy, Andriy I. Stratiichuk, Denys A. Lisnyak, Vladyslav V. Materials (Basel) Article Amorphous Spherical Carbon with Nitrogen (SCN) active carbon has been prepared by carbonization of poly(vinylpyridine-divinylbenzene) (PVPDVB) copolymer. The PVPDVB dehydrogenation copolymer has been quantum chemically (QC) simulated using cluster and periodic models. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy dispersive X-ray (EDX) studies of the resulting product have conformed the QC computation results. Great structural similarity is found both at the nano- and micro-levels between the N-doped SCN carbon and its pure carbonic SKS analog. Molecular Diversity Preservation International 2009-09-07 /pmc/articles/PMC5445732/ http://dx.doi.org/10.3390/ma2031239 Text en © 2009 by the authors. Licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Khavryuchenko, Volodymyr D.
Khavryuchenko, Oleksiy V.
Shkilnyy, Andriy I.
Stratiichuk, Denys A.
Lisnyak, Vladyslav V.
Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer
title Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer
title_full Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer
title_fullStr Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer
title_full_unstemmed Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer
title_short Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer
title_sort characterization by sem, tem and quantum-chemical simulations of the spherical carbon with nitrogen (scn) active carbon produced by thermal decomposition of poly(vinylpyridine-divinylbenzene) copolymer
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5445732/
http://dx.doi.org/10.3390/ma2031239
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