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The Electronic Structure and Secondary Pyroelectric Properties of Lithium Tetraborate
We review the pyroelectric properties and electronic structure of Li(2)B(4)O(7)(110) and Li(2)B(4)O(7)(100) surfaces. There is evidence for a pyroelectric current along the [110] direction of stoichiometric Li(2)B(4)O(7) so that the pyroelectric coefficient is nonzero but roughly 10(3) smaller than...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5445769/ https://www.ncbi.nlm.nih.gov/pubmed/28883341 http://dx.doi.org/10.3390/ma3094550 |
Sumario: | We review the pyroelectric properties and electronic structure of Li(2)B(4)O(7)(110) and Li(2)B(4)O(7)(100) surfaces. There is evidence for a pyroelectric current along the [110] direction of stoichiometric Li(2)B(4)O(7) so that the pyroelectric coefficient is nonzero but roughly 10(3) smaller than along the [001] direction of spontaneous polarization. Abrupt decreases in the pyroelectric coefficient along the [110] direction can be correlated with anomalies in the elastic stiffness [Formula: see text] contributing to the concept that the pyroelectric coefficient is not simply a vector but has qualities of a tensor, as expected. The time dependent surface photovoltaic charging suggests that surface charging is dependent on crystal orientation and doping, as well as temperature. |
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