New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity

We present new element organic frameworks based on Sn, Sb and Bi atoms connected via organic linkers by element-carbon bonds. The open frameworks are characterized by specific surface areas (BET) of up to 445 m(2) g(-1) and a good stability under ambient conditions resulting from a highly hydrophobi...

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Autores principales: Fritsch, Julia, Rose, Marcus, Wollmann, Philipp, Böhlmann, Winfried, Kaskel, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5445839/
http://dx.doi.org/10.3390/ma3042447
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author Fritsch, Julia
Rose, Marcus
Wollmann, Philipp
Böhlmann, Winfried
Kaskel, Stefan
author_facet Fritsch, Julia
Rose, Marcus
Wollmann, Philipp
Böhlmann, Winfried
Kaskel, Stefan
author_sort Fritsch, Julia
collection PubMed
description We present new element organic frameworks based on Sn, Sb and Bi atoms connected via organic linkers by element-carbon bonds. The open frameworks are characterized by specific surface areas (BET) of up to 445 m(2) g(-1) and a good stability under ambient conditions resulting from a highly hydrophobic inner surface. They show good performance as heterogeneous catalysts in the cyanosylilation of benzaldehyde as a test reaction. Due to their catalytic activity, this class of materials might be able to replace common homogeneous element-organic and often highly toxic catalysts especially in the food industry.
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spelling pubmed-54458392017-07-28 New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity Fritsch, Julia Rose, Marcus Wollmann, Philipp Böhlmann, Winfried Kaskel, Stefan Materials (Basel) Article We present new element organic frameworks based on Sn, Sb and Bi atoms connected via organic linkers by element-carbon bonds. The open frameworks are characterized by specific surface areas (BET) of up to 445 m(2) g(-1) and a good stability under ambient conditions resulting from a highly hydrophobic inner surface. They show good performance as heterogeneous catalysts in the cyanosylilation of benzaldehyde as a test reaction. Due to their catalytic activity, this class of materials might be able to replace common homogeneous element-organic and often highly toxic catalysts especially in the food industry. Molecular Diversity Preservation International 2010-03-30 /pmc/articles/PMC5445839/ http://dx.doi.org/10.3390/ma3042447 Text en © 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Fritsch, Julia
Rose, Marcus
Wollmann, Philipp
Böhlmann, Winfried
Kaskel, Stefan
New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity
title New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity
title_full New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity
title_fullStr New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity
title_full_unstemmed New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity
title_short New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity
title_sort new element organic frameworks based on sn, sb, and bi, with permanent porosity and high catalytic activity
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5445839/
http://dx.doi.org/10.3390/ma3042447
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