Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds

Olefin metathesis using ruthenium carbene complexes is a useful method in synthetic organic chemistry. Enyne metathesis is also catalyzed by these complexes and various carbo- and heterocycles could be synthesized from the corresponding enynes. Dienyne metathesis, cross enyne metathesis and ring-ope...

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Detalles Bibliográficos
Autor principal: Mori, Miwako
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5445882/
http://dx.doi.org/10.3390/ma3032087
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author Mori, Miwako
author_facet Mori, Miwako
author_sort Mori, Miwako
collection PubMed
description Olefin metathesis using ruthenium carbene complexes is a useful method in synthetic organic chemistry. Enyne metathesis is also catalyzed by these complexes and various carbo- and heterocycles could be synthesized from the corresponding enynes. Dienyne metathesis, cross enyne metathesis and ring-opening enyne metathesis have been further developed. Various complicated compounds, such as the natural products and the related biologically active substances, could be synthesized using these metatheses reactions. Skeletal reorganization using the transition metals and metallotropic rearrangement are also discussed.
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spelling pubmed-54458822017-07-28 Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds Mori, Miwako Materials (Basel) Review Olefin metathesis using ruthenium carbene complexes is a useful method in synthetic organic chemistry. Enyne metathesis is also catalyzed by these complexes and various carbo- and heterocycles could be synthesized from the corresponding enynes. Dienyne metathesis, cross enyne metathesis and ring-opening enyne metathesis have been further developed. Various complicated compounds, such as the natural products and the related biologically active substances, could be synthesized using these metatheses reactions. Skeletal reorganization using the transition metals and metallotropic rearrangement are also discussed. Molecular Diversity Preservation International 2010-03-19 /pmc/articles/PMC5445882/ http://dx.doi.org/10.3390/ma3032087 Text en © 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Review
Mori, Miwako
Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds
title Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds
title_full Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds
title_fullStr Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds
title_full_unstemmed Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds
title_short Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds
title_sort recent progress on enyne metathesis: its application to syntheses of natural products and related compounds
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5445882/
http://dx.doi.org/10.3390/ma3032087
work_keys_str_mv AT morimiwako recentprogressonenynemetathesisitsapplicationtosynthesesofnaturalproductsandrelatedcompounds

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