CO(2) Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System

The cooperative catalytic activity of several metal corrole complexes in combination with tetrabutyl‐ammonium bromide (TBAB) has been investigated for the reaction of epoxides with CO(2) leading to cyclic carbonates. It was found that the use of just 0.05 mol % of a manganese(III)corrole with 2 mol ...

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Detalles Bibliográficos
Autores principales: Tiffner, Maximilian, Gonglach, Sabrina, Haas, Michael, Schöfberger, Wolfgang, Waser, Mario
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5446785/
https://www.ncbi.nlm.nih.gov/pubmed/28378897
http://dx.doi.org/10.1002/asia.201700354
Descripción
Sumario:The cooperative catalytic activity of several metal corrole complexes in combination with tetrabutyl‐ammonium bromide (TBAB) has been investigated for the reaction of epoxides with CO(2) leading to cyclic carbonates. It was found that the use of just 0.05 mol % of a manganese(III)corrole with 2 mol % TBAB exhibits excellent catalytic activity under an atmosphere of CO(2).

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