CO(2) Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System

The cooperative catalytic activity of several metal corrole complexes in combination with tetrabutyl‐ammonium bromide (TBAB) has been investigated for the reaction of epoxides with CO(2) leading to cyclic carbonates. It was found that the use of just 0.05 mol % of a manganese(III)corrole with 2 mol ...

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Autores principales: Tiffner, Maximilian, Gonglach, Sabrina, Haas, Michael, Schöfberger, Wolfgang, Waser, Mario
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5446785/
https://www.ncbi.nlm.nih.gov/pubmed/28378897
http://dx.doi.org/10.1002/asia.201700354
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author Tiffner, Maximilian
Gonglach, Sabrina
Haas, Michael
Schöfberger, Wolfgang
Waser, Mario
author_facet Tiffner, Maximilian
Gonglach, Sabrina
Haas, Michael
Schöfberger, Wolfgang
Waser, Mario
author_sort Tiffner, Maximilian
collection PubMed
description The cooperative catalytic activity of several metal corrole complexes in combination with tetrabutyl‐ammonium bromide (TBAB) has been investigated for the reaction of epoxides with CO(2) leading to cyclic carbonates. It was found that the use of just 0.05 mol % of a manganese(III)corrole with 2 mol % TBAB exhibits excellent catalytic activity under an atmosphere of CO(2).
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spelling pubmed-54467852017-05-27 CO(2) Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System Tiffner, Maximilian Gonglach, Sabrina Haas, Michael Schöfberger, Wolfgang Waser, Mario Chem Asian J Communications The cooperative catalytic activity of several metal corrole complexes in combination with tetrabutyl‐ammonium bromide (TBAB) has been investigated for the reaction of epoxides with CO(2) leading to cyclic carbonates. It was found that the use of just 0.05 mol % of a manganese(III)corrole with 2 mol % TBAB exhibits excellent catalytic activity under an atmosphere of CO(2). John Wiley and Sons Inc. 2017-04-20 2017-05-18 /pmc/articles/PMC5446785/ /pubmed/28378897 http://dx.doi.org/10.1002/asia.201700354 Text en ©2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Tiffner, Maximilian
Gonglach, Sabrina
Haas, Michael
Schöfberger, Wolfgang
Waser, Mario
CO(2) Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System
title CO(2) Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System
title_full CO(2) Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System
title_fullStr CO(2) Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System
title_full_unstemmed CO(2) Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System
title_short CO(2) Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System
title_sort co(2) fixation with epoxides under mild conditions with a cooperative metal corrole/quaternary ammonium salt catalyst system
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5446785/
https://www.ncbi.nlm.nih.gov/pubmed/28378897
http://dx.doi.org/10.1002/asia.201700354
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