{Fe(6)O(2)}-Based Assembly of a Tetradecanuclear Iron Nanocluster

The tetradecanuclear Fe(III) pivalate nanocluster [Fe(14)O(10)(OH)(4)(Piv)(18)], comprising a new type of metal oxide framework, has been solvothermally synthesized from a hexanuclear iron pivalate precursor in dichlormethane/acetonitrile solution. Magnetic measurements indicate the presence of very...

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Detalles Bibliográficos
Autores principales: Baca, Svetlana G., Speldrich, Manfred, Ellern, Arkady, Kögerler, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5448473/
https://www.ncbi.nlm.nih.gov/pubmed/28879990
http://dx.doi.org/10.3390/ma4010300
Descripción
Sumario:The tetradecanuclear Fe(III) pivalate nanocluster [Fe(14)O(10)(OH)(4)(Piv)(18)], comprising a new type of metal oxide framework, has been solvothermally synthesized from a hexanuclear iron pivalate precursor in dichlormethane/acetonitrile solution. Magnetic measurements indicate the presence of very strong antiferromagnetic interactions in the cluster core.

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