Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain

We synthesized poly(isothianaphthene methine)s with chiral alkyl chains in the substituent. Resultant polymers are soluble in THF and CHCl(3). Structure of the polymers was characterized with FT-IR, FT-Raman, and UV-Vis-NIR optical absorption spectroscopy. They showed low-bandgap both in solution an...

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Autores principales: Innami, Yu, Kawashima, Hirotsugu, Kiebooms, Rafaël H. L., Aizawa, Hideaki, Matsuishi, Kiyoto, Goto, Hiromasa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5448907/
https://www.ncbi.nlm.nih.gov/pubmed/28817047
http://dx.doi.org/10.3390/ma5020317
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author Innami, Yu
Kawashima, Hirotsugu
Kiebooms, Rafaël H. L.
Aizawa, Hideaki
Matsuishi, Kiyoto
Goto, Hiromasa
author_facet Innami, Yu
Kawashima, Hirotsugu
Kiebooms, Rafaël H. L.
Aizawa, Hideaki
Matsuishi, Kiyoto
Goto, Hiromasa
author_sort Innami, Yu
collection PubMed
description We synthesized poly(isothianaphthene methine)s with chiral alkyl chains in the substituent. Resultant polymers are soluble in THF and CHCl(3). Structure of the polymers was characterized with FT-IR, FT-Raman, and UV-Vis-NIR optical absorption spectroscopy. They showed low-bandgap both in solution and in a form of film. Optical activity of the polymers was confirmed with optical rotatory dispersion. Doping effects on the polymer were also examined with UV-Vis-NIR spectroscopy and ESR measurement.
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spelling pubmed-54489072017-07-28 Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain Innami, Yu Kawashima, Hirotsugu Kiebooms, Rafaël H. L. Aizawa, Hideaki Matsuishi, Kiyoto Goto, Hiromasa Materials (Basel) Article We synthesized poly(isothianaphthene methine)s with chiral alkyl chains in the substituent. Resultant polymers are soluble in THF and CHCl(3). Structure of the polymers was characterized with FT-IR, FT-Raman, and UV-Vis-NIR optical absorption spectroscopy. They showed low-bandgap both in solution and in a form of film. Optical activity of the polymers was confirmed with optical rotatory dispersion. Doping effects on the polymer were also examined with UV-Vis-NIR spectroscopy and ESR measurement. MDPI 2012-02-16 /pmc/articles/PMC5448907/ /pubmed/28817047 http://dx.doi.org/10.3390/ma5020317 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Innami, Yu
Kawashima, Hirotsugu
Kiebooms, Rafaël H. L.
Aizawa, Hideaki
Matsuishi, Kiyoto
Goto, Hiromasa
Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain
title Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain
title_full Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain
title_fullStr Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain
title_full_unstemmed Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain
title_short Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain
title_sort synthesis and properties of poly(isothianaphthene methine)s with chiral alkyl chain
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5448907/
https://www.ncbi.nlm.nih.gov/pubmed/28817047
http://dx.doi.org/10.3390/ma5020317
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