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Polysulfide-1-oxides react with peroxyl radicals as quickly as hindered phenolic antioxidants and do so by a surprising concerted homolytic substitution

Polysulfides are important additives to a wide variety of industrial and consumer products and figure prominently in the chemistry and biology of garlic and related medicinal plants. Although their antioxidant activity in biological contexts has received only recent attention, they have long been as...

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Detalles Bibliográficos
Autores principales: Chauvin, Jean-Philippe R., Haidasz, Evan A., Griesser, Markus, Pratt, Derek A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5450444/
https://www.ncbi.nlm.nih.gov/pubmed/28567247
http://dx.doi.org/10.1039/c6sc01434h