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Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics

In this review, the main synthetic aspects and properties of fluorinated arylenevinylene compounds, both oligomers and polymers, are summarized and analyzed. Starting from vinyl organotin derivatives and aryl halides, the Stille cross-coupling reaction has been successfully applied as a versatile sy...

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Autores principales: Martinelli, Carmela, Farinola, Gianluca M., Pinto, Vita, Cardone, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5452319/
https://www.ncbi.nlm.nih.gov/pubmed/28809206
http://dx.doi.org/10.3390/ma6041205
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author Martinelli, Carmela
Farinola, Gianluca M.
Pinto, Vita
Cardone, Antonio
author_facet Martinelli, Carmela
Farinola, Gianluca M.
Pinto, Vita
Cardone, Antonio
author_sort Martinelli, Carmela
collection PubMed
description In this review, the main synthetic aspects and properties of fluorinated arylenevinylene compounds, both oligomers and polymers, are summarized and analyzed. Starting from vinyl organotin derivatives and aryl halides, the Stille cross-coupling reaction has been successfully applied as a versatile synthetic protocol to prepare a wide series of π-conjugated compounds, selectively fluorinated on the aromatic and/or vinylene units. The impact of fluoro-functionalization on properties, the solid state organization and intermolecular interactions of the synthesized compounds are discussed, also in comparison with the non-fluorinated counterparts. Luminescent and photovoltaic applications are also discussed, highlighting the role of fluorine on the performance of devices.
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spelling pubmed-54523192017-07-28 Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics Martinelli, Carmela Farinola, Gianluca M. Pinto, Vita Cardone, Antonio Materials (Basel) Review In this review, the main synthetic aspects and properties of fluorinated arylenevinylene compounds, both oligomers and polymers, are summarized and analyzed. Starting from vinyl organotin derivatives and aryl halides, the Stille cross-coupling reaction has been successfully applied as a versatile synthetic protocol to prepare a wide series of π-conjugated compounds, selectively fluorinated on the aromatic and/or vinylene units. The impact of fluoro-functionalization on properties, the solid state organization and intermolecular interactions of the synthesized compounds are discussed, also in comparison with the non-fluorinated counterparts. Luminescent and photovoltaic applications are also discussed, highlighting the role of fluorine on the performance of devices. MDPI 2013-03-25 /pmc/articles/PMC5452319/ /pubmed/28809206 http://dx.doi.org/10.3390/ma6041205 Text en © 2013 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Review
Martinelli, Carmela
Farinola, Gianluca M.
Pinto, Vita
Cardone, Antonio
Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics
title Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics
title_full Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics
title_fullStr Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics
title_full_unstemmed Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics
title_short Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics
title_sort synthetic aspects and electro-optical properties of fluorinated arylenevinylenes for luminescence and photovoltaics
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5452319/
https://www.ncbi.nlm.nih.gov/pubmed/28809206
http://dx.doi.org/10.3390/ma6041205
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