Cargando…
Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics
In this review, the main synthetic aspects and properties of fluorinated arylenevinylene compounds, both oligomers and polymers, are summarized and analyzed. Starting from vinyl organotin derivatives and aryl halides, the Stille cross-coupling reaction has been successfully applied as a versatile sy...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5452319/ https://www.ncbi.nlm.nih.gov/pubmed/28809206 http://dx.doi.org/10.3390/ma6041205 |
_version_ | 1783240387217850368 |
---|---|
author | Martinelli, Carmela Farinola, Gianluca M. Pinto, Vita Cardone, Antonio |
author_facet | Martinelli, Carmela Farinola, Gianluca M. Pinto, Vita Cardone, Antonio |
author_sort | Martinelli, Carmela |
collection | PubMed |
description | In this review, the main synthetic aspects and properties of fluorinated arylenevinylene compounds, both oligomers and polymers, are summarized and analyzed. Starting from vinyl organotin derivatives and aryl halides, the Stille cross-coupling reaction has been successfully applied as a versatile synthetic protocol to prepare a wide series of π-conjugated compounds, selectively fluorinated on the aromatic and/or vinylene units. The impact of fluoro-functionalization on properties, the solid state organization and intermolecular interactions of the synthesized compounds are discussed, also in comparison with the non-fluorinated counterparts. Luminescent and photovoltaic applications are also discussed, highlighting the role of fluorine on the performance of devices. |
format | Online Article Text |
id | pubmed-5452319 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-54523192017-07-28 Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics Martinelli, Carmela Farinola, Gianluca M. Pinto, Vita Cardone, Antonio Materials (Basel) Review In this review, the main synthetic aspects and properties of fluorinated arylenevinylene compounds, both oligomers and polymers, are summarized and analyzed. Starting from vinyl organotin derivatives and aryl halides, the Stille cross-coupling reaction has been successfully applied as a versatile synthetic protocol to prepare a wide series of π-conjugated compounds, selectively fluorinated on the aromatic and/or vinylene units. The impact of fluoro-functionalization on properties, the solid state organization and intermolecular interactions of the synthesized compounds are discussed, also in comparison with the non-fluorinated counterparts. Luminescent and photovoltaic applications are also discussed, highlighting the role of fluorine on the performance of devices. MDPI 2013-03-25 /pmc/articles/PMC5452319/ /pubmed/28809206 http://dx.doi.org/10.3390/ma6041205 Text en © 2013 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/). |
spellingShingle | Review Martinelli, Carmela Farinola, Gianluca M. Pinto, Vita Cardone, Antonio Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics |
title | Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics |
title_full | Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics |
title_fullStr | Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics |
title_full_unstemmed | Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics |
title_short | Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics |
title_sort | synthetic aspects and electro-optical properties of fluorinated arylenevinylenes for luminescence and photovoltaics |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5452319/ https://www.ncbi.nlm.nih.gov/pubmed/28809206 http://dx.doi.org/10.3390/ma6041205 |
work_keys_str_mv | AT martinellicarmela syntheticaspectsandelectroopticalpropertiesoffluorinatedarylenevinylenesforluminescenceandphotovoltaics AT farinolagianlucam syntheticaspectsandelectroopticalpropertiesoffluorinatedarylenevinylenesforluminescenceandphotovoltaics AT pintovita syntheticaspectsandelectroopticalpropertiesoffluorinatedarylenevinylenesforluminescenceandphotovoltaics AT cardoneantonio syntheticaspectsandelectroopticalpropertiesoffluorinatedarylenevinylenesforluminescenceandphotovoltaics |