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Synthesis, Molecular Structure and Cytotoxicity of Molecular Materials Based on Water Soluble Half-Sandwich Rh(III) and Ir(III) Tetranuclear Metalla-Cycles

The neutral dinuclear complexes [(η(5)-C(5)Me(5))(2)Rh(2)(μ-dhnq)Cl(2)] (1) and [(η(5)-C(5)Me(5))(2)Ir(2)(μ-dhnq)Cl(2)] (2) (dhnqH(2) = 5,8-dihydroxy-1,4-naphthoquinone) were obtained from the reaction of [(η(5)-C(5)Me(5))M(μ-Cl)Cl](2) (M = Rh, Ir) with dhnqH(2) in the presence of CH(3)COONa. Treatm...

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Detalles Bibliográficos
Autores principales: Gupta, Gajendra, Murray, Benjamin S., Dyson, Paul J., Therrien, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5452765/
https://www.ncbi.nlm.nih.gov/pubmed/28788394
http://dx.doi.org/10.3390/ma6115352