A Self-Assembled Electro-Active M(8)L(4) Cage Based on Tetrathiafulvalene Ligands

Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)(2) (M = Pd or Pt; dppf = 1,1′-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are...

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Detalles Bibliográficos
Autores principales: Goeb, Sébastien, Bivaud, Sébastien, Croué, Vincent, Vajpayee, Vaishali, Allain, Magali, Sallé, Marc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5453136/
https://www.ncbi.nlm.nih.gov/pubmed/28788478
http://dx.doi.org/10.3390/ma7010611
Descripción
Sumario:Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)(2) (M = Pd or Pt; dppf = 1,1′-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized.

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