A Self-Assembled Electro-Active M(8)L(4) Cage Based on Tetrathiafulvalene Ligands

Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)(2) (M = Pd or Pt; dppf = 1,1′-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are...

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Detalles Bibliográficos
Autores principales: Goeb, Sébastien, Bivaud, Sébastien, Croué, Vincent, Vajpayee, Vaishali, Allain, Magali, Sallé, Marc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5453136/
https://www.ncbi.nlm.nih.gov/pubmed/28788478
http://dx.doi.org/10.3390/ma7010611
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author Goeb, Sébastien
Bivaud, Sébastien
Croué, Vincent
Vajpayee, Vaishali
Allain, Magali
Sallé, Marc
author_facet Goeb, Sébastien
Bivaud, Sébastien
Croué, Vincent
Vajpayee, Vaishali
Allain, Magali
Sallé, Marc
author_sort Goeb, Sébastien
collection PubMed
description Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)(2) (M = Pd or Pt; dppf = 1,1′-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized.
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spelling pubmed-54531362017-07-28 A Self-Assembled Electro-Active M(8)L(4) Cage Based on Tetrathiafulvalene Ligands Goeb, Sébastien Bivaud, Sébastien Croué, Vincent Vajpayee, Vaishali Allain, Magali Sallé, Marc Materials (Basel) Article Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)(2) (M = Pd or Pt; dppf = 1,1′-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized. MDPI 2014-01-22 /pmc/articles/PMC5453136/ /pubmed/28788478 http://dx.doi.org/10.3390/ma7010611 Text en © 2014 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Goeb, Sébastien
Bivaud, Sébastien
Croué, Vincent
Vajpayee, Vaishali
Allain, Magali
Sallé, Marc
A Self-Assembled Electro-Active M(8)L(4) Cage Based on Tetrathiafulvalene Ligands
title A Self-Assembled Electro-Active M(8)L(4) Cage Based on Tetrathiafulvalene Ligands
title_full A Self-Assembled Electro-Active M(8)L(4) Cage Based on Tetrathiafulvalene Ligands
title_fullStr A Self-Assembled Electro-Active M(8)L(4) Cage Based on Tetrathiafulvalene Ligands
title_full_unstemmed A Self-Assembled Electro-Active M(8)L(4) Cage Based on Tetrathiafulvalene Ligands
title_short A Self-Assembled Electro-Active M(8)L(4) Cage Based on Tetrathiafulvalene Ligands
title_sort self-assembled electro-active m(8)l(4) cage based on tetrathiafulvalene ligands
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5453136/
https://www.ncbi.nlm.nih.gov/pubmed/28788478
http://dx.doi.org/10.3390/ma7010611
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