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Preparation and Chemical Properties of π-Conjugated Polymers Containing Indigo Unit in the Main Chain
π-Conjugated polymers based on indigo unit were prepared. Dehalogenative polycondensation of N-hexyl-6,6′-dibromoindigo with a zerovalent nickel complex gave a homopolymer, P(HexI), in 77% yield. Copolymer of N-hexyl-indigo and pyridine, P(HexI-Py), was also prepared in 50% yield. P(HexI) showed goo...
Autores principales: | Fukumoto, Hiroki, Nakajima, Hisashi, Kojima, Takahiro, Yamamoto, Takakazu |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5453285/ https://www.ncbi.nlm.nih.gov/pubmed/28788554 http://dx.doi.org/10.3390/ma7032030 |
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