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Liquid Crystalline Esters of Dibenzophenazines

A series of esters of 2,3,6,7-tetrakis(hexyloxy)dibenzo[a,c]phenazine-11-carboxylic acid was prepared in order to probe the effects of the ester groups on the liquid crystalline behavior. These compounds exhibit columnar hexagonal phases over broad temperature ranges. Variations in chain length, bra...

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Detalles Bibliográficos
Autores principales: Bozek, Kevin John Anthony, Ho, Kuan I, Saint-Martin, Tom, Argyropoulos, Panos, Williams, Vance E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5455216/
https://www.ncbi.nlm.nih.gov/pubmed/28787937
http://dx.doi.org/10.3390/ma8010270
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author Bozek, Kevin John Anthony
Ho, Kuan I
Saint-Martin, Tom
Argyropoulos, Panos
Williams, Vance E.
author_facet Bozek, Kevin John Anthony
Ho, Kuan I
Saint-Martin, Tom
Argyropoulos, Panos
Williams, Vance E.
author_sort Bozek, Kevin John Anthony
collection PubMed
description A series of esters of 2,3,6,7-tetrakis(hexyloxy)dibenzo[a,c]phenazine-11-carboxylic acid was prepared in order to probe the effects of the ester groups on the liquid crystalline behavior. These compounds exhibit columnar hexagonal phases over broad temperature ranges. Variations in chain length, branching, terminal groups, and the presence of cyclic groups were found to modify transition temperatures without substantially destabilizing the mesophase range.
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spelling pubmed-54552162017-07-28 Liquid Crystalline Esters of Dibenzophenazines Bozek, Kevin John Anthony Ho, Kuan I Saint-Martin, Tom Argyropoulos, Panos Williams, Vance E. Materials (Basel) Article A series of esters of 2,3,6,7-tetrakis(hexyloxy)dibenzo[a,c]phenazine-11-carboxylic acid was prepared in order to probe the effects of the ester groups on the liquid crystalline behavior. These compounds exhibit columnar hexagonal phases over broad temperature ranges. Variations in chain length, branching, terminal groups, and the presence of cyclic groups were found to modify transition temperatures without substantially destabilizing the mesophase range. MDPI 2015-01-14 /pmc/articles/PMC5455216/ /pubmed/28787937 http://dx.doi.org/10.3390/ma8010270 Text en © 2015 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Bozek, Kevin John Anthony
Ho, Kuan I
Saint-Martin, Tom
Argyropoulos, Panos
Williams, Vance E.
Liquid Crystalline Esters of Dibenzophenazines
title Liquid Crystalline Esters of Dibenzophenazines
title_full Liquid Crystalline Esters of Dibenzophenazines
title_fullStr Liquid Crystalline Esters of Dibenzophenazines
title_full_unstemmed Liquid Crystalline Esters of Dibenzophenazines
title_short Liquid Crystalline Esters of Dibenzophenazines
title_sort liquid crystalline esters of dibenzophenazines
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5455216/
https://www.ncbi.nlm.nih.gov/pubmed/28787937
http://dx.doi.org/10.3390/ma8010270
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