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3D Microstructure Effects in Ni-YSZ Anodes: Influence of TPB Lengths on the Electrochemical Performance

3D microstructure-performance relationships in Ni-YSZ anodes for electrolyte-supported cells are investigated in terms of the correlation between the triple phase boundary (TPB) length and polarization resistance (R(pol)). Three different Ni-YSZ anodes of varying microstructure are subjected to eigh...

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Autores principales: Pecho, Omar M., Mai, Andreas, Münch, Beat, Hocker, Thomas, Flatt, Robert J., Holzer, Lorenz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5455394/
https://www.ncbi.nlm.nih.gov/pubmed/28793624
http://dx.doi.org/10.3390/ma8105370
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author Pecho, Omar M.
Mai, Andreas
Münch, Beat
Hocker, Thomas
Flatt, Robert J.
Holzer, Lorenz
author_facet Pecho, Omar M.
Mai, Andreas
Münch, Beat
Hocker, Thomas
Flatt, Robert J.
Holzer, Lorenz
author_sort Pecho, Omar M.
collection PubMed
description 3D microstructure-performance relationships in Ni-YSZ anodes for electrolyte-supported cells are investigated in terms of the correlation between the triple phase boundary (TPB) length and polarization resistance (R(pol)). Three different Ni-YSZ anodes of varying microstructure are subjected to eight reduction-oxidation (redox) cycles at 950 °C. In general the TPB lengths correlate with anode performance. However, the quantitative results also show that there is no simplistic relationship between TPB and R(pol). The degradation mechanism strongly depends on the initial microstructure. Finer microstructures exhibit lower degradation rates of TPB and R(pol). In fine microstructures, TPB loss is found to be due to Ni coarsening, while in coarse microstructures reduction of active TPB results mainly from loss of YSZ percolation. The latter is attributed to weak bottlenecks associated with lower sintering activity of the coarse YSZ. The coarse anode suffers from complete loss of YSZ connectivity and associated drop of TPB(active) by 93%. Surprisingly, this severe microstructure degradation did not lead to electrochemical failure. Mechanistic scenarios are discussed for different anode microstructures. These scenarios are based on a model for coupled charge transfer and transport, which allows using TPB and effective properties as input. The mechanistic scenarios describe the microstructure influence on current distributions, which explains the observed complex relationship between TPB lengths and anode performances. The observed loss of YSZ percolation in the coarse anode is not detrimental because the electrochemical activity is concentrated in a narrow active layer. The anode performance can be predicted reliably if the volume-averaged properties (TPB(active), effective ionic conductivity) are corrected for the so-called short-range effect, which is particularly important in cases with a narrow active layer.
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spelling pubmed-54553942017-07-28 3D Microstructure Effects in Ni-YSZ Anodes: Influence of TPB Lengths on the Electrochemical Performance Pecho, Omar M. Mai, Andreas Münch, Beat Hocker, Thomas Flatt, Robert J. Holzer, Lorenz Materials (Basel) Article 3D microstructure-performance relationships in Ni-YSZ anodes for electrolyte-supported cells are investigated in terms of the correlation between the triple phase boundary (TPB) length and polarization resistance (R(pol)). Three different Ni-YSZ anodes of varying microstructure are subjected to eight reduction-oxidation (redox) cycles at 950 °C. In general the TPB lengths correlate with anode performance. However, the quantitative results also show that there is no simplistic relationship between TPB and R(pol). The degradation mechanism strongly depends on the initial microstructure. Finer microstructures exhibit lower degradation rates of TPB and R(pol). In fine microstructures, TPB loss is found to be due to Ni coarsening, while in coarse microstructures reduction of active TPB results mainly from loss of YSZ percolation. The latter is attributed to weak bottlenecks associated with lower sintering activity of the coarse YSZ. The coarse anode suffers from complete loss of YSZ connectivity and associated drop of TPB(active) by 93%. Surprisingly, this severe microstructure degradation did not lead to electrochemical failure. Mechanistic scenarios are discussed for different anode microstructures. These scenarios are based on a model for coupled charge transfer and transport, which allows using TPB and effective properties as input. The mechanistic scenarios describe the microstructure influence on current distributions, which explains the observed complex relationship between TPB lengths and anode performances. The observed loss of YSZ percolation in the coarse anode is not detrimental because the electrochemical activity is concentrated in a narrow active layer. The anode performance can be predicted reliably if the volume-averaged properties (TPB(active), effective ionic conductivity) are corrected for the so-called short-range effect, which is particularly important in cases with a narrow active layer. MDPI 2015-10-21 /pmc/articles/PMC5455394/ /pubmed/28793624 http://dx.doi.org/10.3390/ma8105370 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Pecho, Omar M.
Mai, Andreas
Münch, Beat
Hocker, Thomas
Flatt, Robert J.
Holzer, Lorenz
3D Microstructure Effects in Ni-YSZ Anodes: Influence of TPB Lengths on the Electrochemical Performance
title 3D Microstructure Effects in Ni-YSZ Anodes: Influence of TPB Lengths on the Electrochemical Performance
title_full 3D Microstructure Effects in Ni-YSZ Anodes: Influence of TPB Lengths on the Electrochemical Performance
title_fullStr 3D Microstructure Effects in Ni-YSZ Anodes: Influence of TPB Lengths on the Electrochemical Performance
title_full_unstemmed 3D Microstructure Effects in Ni-YSZ Anodes: Influence of TPB Lengths on the Electrochemical Performance
title_short 3D Microstructure Effects in Ni-YSZ Anodes: Influence of TPB Lengths on the Electrochemical Performance
title_sort 3d microstructure effects in ni-ysz anodes: influence of tpb lengths on the electrochemical performance
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5455394/
https://www.ncbi.nlm.nih.gov/pubmed/28793624
http://dx.doi.org/10.3390/ma8105370
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