Effect of Transition Metal Substitution on the Structure and Properties of a Clathrate-Like Compound Eu(7)Cu(44)As(23)

A series of substitutional solid solutions—Eu(7)Cu(44−x)T(x)As(23) (T = Fe, Co, Ni)—based on a recently discovered clathrate-like compound (Eu(7)Cu(44)As(23)) were synthesized from the elements at 800 °C. Almost up to 50% of Cu can be substituted by Ni, resulting in a linear decrease of the cubic un...

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Detalles Bibliográficos
Autores principales: Plokhikh, Igor V., Charkin, Dmitri O., Verchenko, Valeriy Yu., Ignatyev, Ivan A., Kazakov, Sergey M., Sobolev, Alexey V., Presniakov, Igor A., Tsirlin, Alexander A., Shevelkov, Andrei V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5456878/
https://www.ncbi.nlm.nih.gov/pubmed/28773714
http://dx.doi.org/10.3390/ma9070587

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5456878/
https://www.ncbi.nlm.nih.gov/pubmed/28773714
http://dx.doi.org/10.3390/ma9070587

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