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Effect of Transition Metal Substitution on the Structure and Properties of a Clathrate-Like Compound Eu(7)Cu(44)As(23)
A series of substitutional solid solutions—Eu(7)Cu(44−x)T(x)As(23) (T = Fe, Co, Ni)—based on a recently discovered clathrate-like compound (Eu(7)Cu(44)As(23)) were synthesized from the elements at 800 °C. Almost up to 50% of Cu can be substituted by Ni, resulting in a linear decrease of the cubic un...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5456878/ https://www.ncbi.nlm.nih.gov/pubmed/28773714 http://dx.doi.org/10.3390/ma9070587 |