New Rhenium-Doped SrCo(1−x)Re(x)O(3−δ) Perovskites Performing as Cathodes in Solid Oxide Fuel Cells

In the aim to stabilize novel three-dimensional perovskite oxides based upon SrCoO(3−δ), we have designed and prepared SrCo(1−x)Re(x)O(3−δ) phases (x = 0.05 and 0.10), successfully avoiding the competitive hexagonal 2H polytypes. Their performance as cathode materials in intermediate-temperature solid oxide fuel cells (IT-SOFC) has been investigated. The characterization of these oxides included X-ray (XRD) and in situ temperature-dependent neutron powder diffraction (NPD) experiments for x = 0.10. At room temperature, SrCo(1−x)Re(x)O(3−δ) perovskites are defined in the P4/mmm space group, which corresponds to a subtle tetragonal perovskite superstructure with unit-cell parameters a = b ≈ a(o), c = 2a(o) (a(o) = 3.861 and 3.868 Å, for x = 0.05 and 0.10, respectively). The crystal structure evolves above 380 °C to a simple cubic perovskite unit cell, as observed from in-situ NPD data. The electrical conductivity gave maximum values of 43.5 S·cm(−1) and 51.6 S·cm(−1) for x = 0.05 and x = 0.10, respectively, at 850 °C. The area specific resistance (ASR) polarization resistance determined in symmetrical cells is as low as 0.087 Ω·cm(2) and 0.065 Ω·cm(2) for x = 0.05 and x = 0.10, respectively, at 850 °C. In single test cells these materials generated a maximum power of around 0.6 W/cm(2) at 850 °C with pure H(2) as a fuel, in an electrolyte-supported configuration with La(0.8)Sr(0.2)Ga(0.83)Mg(0.17)O(3−)(δ) (LSGM) as the electrolyte. Therefore, we propose the SrCo(1−x)Re(x)O(3−δ) (x = 0.10 and 0.05) perovskite oxides as promising candidates for cathodes in IT-SOFC.