Synthesis and crystal structure of a new magnesium phosphate Na(3)RbMg(7)(PO(4))(6)

A new magnesium phosphate, Na(3)RbMg(7)(PO(4))(6) [tris­odium rubidium hepta­magnesium hexakis(ortho­phosphate)], has been synthesized as single crystals by the flux method and exhibits a new structure type. Its original structure is built up from MgO(x) (x = 5 and 6) polyhedra linked directly to ea...

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Autores principales: Ben Hamed, Teycir, Boukhris, Amal, Badri, Abdessalem, Ben Amara, Mongi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458299/
https://www.ncbi.nlm.nih.gov/pubmed/28638634
http://dx.doi.org/10.1107/S2056989017006363
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author Ben Hamed, Teycir
Boukhris, Amal
Badri, Abdessalem
Ben Amara, Mongi
author_facet Ben Hamed, Teycir
Boukhris, Amal
Badri, Abdessalem
Ben Amara, Mongi
author_sort Ben Hamed, Teycir
collection PubMed
description A new magnesium phosphate, Na(3)RbMg(7)(PO(4))(6) [tris­odium rubidium hepta­magnesium hexakis(ortho­phosphate)], has been synthesized as single crystals by the flux method and exhibits a new structure type. Its original structure is built up from MgO(x) (x = 5 and 6) polyhedra linked directly to each other through common corners or edges and reinforced by corner-sharing with PO(4) tetra­hedra. The resulting anionic three-dimensional framework leads to the formation of channels along the [010] direction, in which the Na(+) cations are located, while the Rb(+) cations are located in large inter­stitial cavities.
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spelling pubmed-54582992017-06-21 Synthesis and crystal structure of a new magnesium phosphate Na(3)RbMg(7)(PO(4))(6) Ben Hamed, Teycir Boukhris, Amal Badri, Abdessalem Ben Amara, Mongi Acta Crystallogr E Crystallogr Commun Research Communications A new magnesium phosphate, Na(3)RbMg(7)(PO(4))(6) [tris­odium rubidium hepta­magnesium hexakis(ortho­phosphate)], has been synthesized as single crystals by the flux method and exhibits a new structure type. Its original structure is built up from MgO(x) (x = 5 and 6) polyhedra linked directly to each other through common corners or edges and reinforced by corner-sharing with PO(4) tetra­hedra. The resulting anionic three-dimensional framework leads to the formation of channels along the [010] direction, in which the Na(+) cations are located, while the Rb(+) cations are located in large inter­stitial cavities. International Union of Crystallography 2017-05-05 /pmc/articles/PMC5458299/ /pubmed/28638634 http://dx.doi.org/10.1107/S2056989017006363 Text en © Ben Hamed et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Ben Hamed, Teycir
Boukhris, Amal
Badri, Abdessalem
Ben Amara, Mongi
Synthesis and crystal structure of a new magnesium phosphate Na(3)RbMg(7)(PO(4))(6)
title Synthesis and crystal structure of a new magnesium phosphate Na(3)RbMg(7)(PO(4))(6)
title_full Synthesis and crystal structure of a new magnesium phosphate Na(3)RbMg(7)(PO(4))(6)
title_fullStr Synthesis and crystal structure of a new magnesium phosphate Na(3)RbMg(7)(PO(4))(6)
title_full_unstemmed Synthesis and crystal structure of a new magnesium phosphate Na(3)RbMg(7)(PO(4))(6)
title_short Synthesis and crystal structure of a new magnesium phosphate Na(3)RbMg(7)(PO(4))(6)
title_sort synthesis and crystal structure of a new magnesium phosphate na(3)rbmg(7)(po(4))(6)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458299/
https://www.ncbi.nlm.nih.gov/pubmed/28638634
http://dx.doi.org/10.1107/S2056989017006363
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