Cargando…

Crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κS]bis­(tri­phenyl­phosphane-κP)silver(I)

In the title compound, [AgCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetra­hedral coordination environment formed by P atoms from two tri­phenyl­phosphane ligands, one terminal S atom from the 1-(4-nitro­phen­yl)thio­urea ligand and a chloride ion. In the crystal, bifurc...

Descripción completa

Detalles Bibliográficos
Autores principales: Nimthong-Roldán, Arunpatcha, Sripa, Paramee, Wattanakanjana, Yupa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458302/
https://www.ncbi.nlm.nih.gov/pubmed/28638637
http://dx.doi.org/10.1107/S2056989017006405
Descripción
Sumario:In the title compound, [AgCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetra­hedral coordination environment formed by P atoms from two tri­phenyl­phosphane ligands, one terminal S atom from the 1-(4-nitro­phen­yl)thio­urea ligand and a chloride ion. In the crystal, bifurcated (N—H)2⋯Cl hydrogen bonds [with graph-set motif R (2) (1)(6)] connect complex mol­ecules, forming zigzag chains along [001]. These chains are linked via weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). An intra­molecular N—H⋯Cl hydrogen bond forming an S(6) ring is also observed.