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Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)silver(I)
In the title compound, [AgCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetrahedral coordination environment formed by P atoms from two triphenylphosphane ligands, one terminal S atom from the 1-(4-nitrophenyl)thiourea ligand and a chloride ion. In the crystal, bifurc...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458302/ https://www.ncbi.nlm.nih.gov/pubmed/28638637 http://dx.doi.org/10.1107/S2056989017006405 |
Sumario: | In the title compound, [AgCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetrahedral coordination environment formed by P atoms from two triphenylphosphane ligands, one terminal S atom from the 1-(4-nitrophenyl)thiourea ligand and a chloride ion. In the crystal, bifurcated (N—H)2⋯Cl hydrogen bonds [with graph-set motif R (2) (1)(6)] connect complex molecules, forming zigzag chains along [001]. These chains are linked via weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). An intramolecular N—H⋯Cl hydrogen bond forming an S(6) ring is also observed. |
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