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Crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κS]bis­(tri­phenyl­phosphane-κP)silver(I)

In the title compound, [AgCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetra­hedral coordination environment formed by P atoms from two tri­phenyl­phosphane ligands, one terminal S atom from the 1-(4-nitro­phen­yl)thio­urea ligand and a chloride ion. In the crystal, bifurc...

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Autores principales: Nimthong-Roldán, Arunpatcha, Sripa, Paramee, Wattanakanjana, Yupa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458302/
https://www.ncbi.nlm.nih.gov/pubmed/28638637
http://dx.doi.org/10.1107/S2056989017006405
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author Nimthong-Roldán, Arunpatcha
Sripa, Paramee
Wattanakanjana, Yupa
author_facet Nimthong-Roldán, Arunpatcha
Sripa, Paramee
Wattanakanjana, Yupa
author_sort Nimthong-Roldán, Arunpatcha
collection PubMed
description In the title compound, [AgCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetra­hedral coordination environment formed by P atoms from two tri­phenyl­phosphane ligands, one terminal S atom from the 1-(4-nitro­phen­yl)thio­urea ligand and a chloride ion. In the crystal, bifurcated (N—H)2⋯Cl hydrogen bonds [with graph-set motif R (2) (1)(6)] connect complex mol­ecules, forming zigzag chains along [001]. These chains are linked via weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). An intra­molecular N—H⋯Cl hydrogen bond forming an S(6) ring is also observed.
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spelling pubmed-54583022017-06-21 Crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κS]bis­(tri­phenyl­phosphane-κP)silver(I) Nimthong-Roldán, Arunpatcha Sripa, Paramee Wattanakanjana, Yupa Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [AgCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetra­hedral coordination environment formed by P atoms from two tri­phenyl­phosphane ligands, one terminal S atom from the 1-(4-nitro­phen­yl)thio­urea ligand and a chloride ion. In the crystal, bifurcated (N—H)2⋯Cl hydrogen bonds [with graph-set motif R (2) (1)(6)] connect complex mol­ecules, forming zigzag chains along [001]. These chains are linked via weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). An intra­molecular N—H⋯Cl hydrogen bond forming an S(6) ring is also observed. International Union of Crystallography 2017-05-09 /pmc/articles/PMC5458302/ /pubmed/28638637 http://dx.doi.org/10.1107/S2056989017006405 Text en © Nimthong-Roldán et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Nimthong-Roldán, Arunpatcha
Sripa, Paramee
Wattanakanjana, Yupa
Crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κS]bis­(tri­phenyl­phosphane-κP)silver(I)
title Crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κS]bis­(tri­phenyl­phosphane-κP)silver(I)
title_full Crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κS]bis­(tri­phenyl­phosphane-κP)silver(I)
title_fullStr Crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κS]bis­(tri­phenyl­phosphane-κP)silver(I)
title_full_unstemmed Crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κS]bis­(tri­phenyl­phosphane-κP)silver(I)
title_short Crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κS]bis­(tri­phenyl­phosphane-κP)silver(I)
title_sort crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κs]bis­(tri­phenyl­phosphane-κp)silver(i)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458302/
https://www.ncbi.nlm.nih.gov/pubmed/28638637
http://dx.doi.org/10.1107/S2056989017006405
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