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Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)silver(I)
In the title compound, [AgCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetrahedral coordination environment formed by P atoms from two triphenylphosphane ligands, one terminal S atom from the 1-(4-nitrophenyl)thiourea ligand and a chloride ion. In the crystal, bifurc...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458302/ https://www.ncbi.nlm.nih.gov/pubmed/28638637 http://dx.doi.org/10.1107/S2056989017006405 |
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author | Nimthong-Roldán, Arunpatcha Sripa, Paramee Wattanakanjana, Yupa |
author_facet | Nimthong-Roldán, Arunpatcha Sripa, Paramee Wattanakanjana, Yupa |
author_sort | Nimthong-Roldán, Arunpatcha |
collection | PubMed |
description | In the title compound, [AgCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetrahedral coordination environment formed by P atoms from two triphenylphosphane ligands, one terminal S atom from the 1-(4-nitrophenyl)thiourea ligand and a chloride ion. In the crystal, bifurcated (N—H)2⋯Cl hydrogen bonds [with graph-set motif R (2) (1)(6)] connect complex molecules, forming zigzag chains along [001]. These chains are linked via weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). An intramolecular N—H⋯Cl hydrogen bond forming an S(6) ring is also observed. |
format | Online Article Text |
id | pubmed-5458302 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-54583022017-06-21 Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)silver(I) Nimthong-Roldán, Arunpatcha Sripa, Paramee Wattanakanjana, Yupa Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [AgCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetrahedral coordination environment formed by P atoms from two triphenylphosphane ligands, one terminal S atom from the 1-(4-nitrophenyl)thiourea ligand and a chloride ion. In the crystal, bifurcated (N—H)2⋯Cl hydrogen bonds [with graph-set motif R (2) (1)(6)] connect complex molecules, forming zigzag chains along [001]. These chains are linked via weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). An intramolecular N—H⋯Cl hydrogen bond forming an S(6) ring is also observed. International Union of Crystallography 2017-05-09 /pmc/articles/PMC5458302/ /pubmed/28638637 http://dx.doi.org/10.1107/S2056989017006405 Text en © Nimthong-Roldán et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Nimthong-Roldán, Arunpatcha Sripa, Paramee Wattanakanjana, Yupa Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)silver(I) |
title | Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)silver(I) |
title_full | Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)silver(I) |
title_fullStr | Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)silver(I) |
title_full_unstemmed | Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)silver(I) |
title_short | Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)silver(I) |
title_sort | crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κs]bis(triphenylphosphane-κp)silver(i) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458302/ https://www.ncbi.nlm.nih.gov/pubmed/28638637 http://dx.doi.org/10.1107/S2056989017006405 |
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