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Crystal structure of 2,2′-(ethane-1,2-di­yl)bis­(2,3-di­hydro-1H-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines

In the title compound, C(26)H(24)N(2)O(2), the oxazine moiety is fused to a naphthalene ring system. The asymmetric unit consists of one half of the mol­ecule, which lies about an inversion centre. The C atoms of the ethyl­ene spacer group adopt an anti­periplanar arrangement. The oxazine ring adopt...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, Cepeda-Santamaría, Juan E., Ríos-Motta, Jaime, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458303/
https://www.ncbi.nlm.nih.gov/pubmed/28638638
http://dx.doi.org/10.1107/S2056989017006673
Descripción
Sumario:In the title compound, C(26)H(24)N(2)O(2), the oxazine moiety is fused to a naphthalene ring system. The asymmetric unit consists of one half of the mol­ecule, which lies about an inversion centre. The C atoms of the ethyl­ene spacer group adopt an anti­periplanar arrangement. The oxazine ring adopts a half-chair conformation. In the crystal, supra­molecular chains running along the b axis are formed via short C—H⋯π contacts. The crystal studied was a non-merohedral twin with a fractional contribution of 0.168 (2) of the minor twin component.