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Crystal structure of 2,2′-(ethane-1,2-diyl)bis(2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines
In the title compound, C(26)H(24)N(2)O(2), the oxazine moiety is fused to a naphthalene ring system. The asymmetric unit consists of one half of the molecule, which lies about an inversion centre. The C atoms of the ethylene spacer group adopt an antiperiplanar arrangement. The oxazine ring adopt...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458303/ https://www.ncbi.nlm.nih.gov/pubmed/28638638 http://dx.doi.org/10.1107/S2056989017006673 |
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author | Rivera, Augusto Cepeda-Santamaría, Juan E. Ríos-Motta, Jaime Bolte, Michael |
author_facet | Rivera, Augusto Cepeda-Santamaría, Juan E. Ríos-Motta, Jaime Bolte, Michael |
author_sort | Rivera, Augusto |
collection | PubMed |
description | In the title compound, C(26)H(24)N(2)O(2), the oxazine moiety is fused to a naphthalene ring system. The asymmetric unit consists of one half of the molecule, which lies about an inversion centre. The C atoms of the ethylene spacer group adopt an antiperiplanar arrangement. The oxazine ring adopts a half-chair conformation. In the crystal, supramolecular chains running along the b axis are formed via short C—H⋯π contacts. The crystal studied was a non-merohedral twin with a fractional contribution of 0.168 (2) of the minor twin component. |
format | Online Article Text |
id | pubmed-5458303 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-54583032017-06-21 Crystal structure of 2,2′-(ethane-1,2-diyl)bis(2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines Rivera, Augusto Cepeda-Santamaría, Juan E. Ríos-Motta, Jaime Bolte, Michael Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(26)H(24)N(2)O(2), the oxazine moiety is fused to a naphthalene ring system. The asymmetric unit consists of one half of the molecule, which lies about an inversion centre. The C atoms of the ethylene spacer group adopt an antiperiplanar arrangement. The oxazine ring adopts a half-chair conformation. In the crystal, supramolecular chains running along the b axis are formed via short C—H⋯π contacts. The crystal studied was a non-merohedral twin with a fractional contribution of 0.168 (2) of the minor twin component. International Union of Crystallography 2017-05-09 /pmc/articles/PMC5458303/ /pubmed/28638638 http://dx.doi.org/10.1107/S2056989017006673 Text en © Rivera et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Rivera, Augusto Cepeda-Santamaría, Juan E. Ríos-Motta, Jaime Bolte, Michael Crystal structure of 2,2′-(ethane-1,2-diyl)bis(2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines |
title | Crystal structure of 2,2′-(ethane-1,2-diyl)bis(2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines |
title_full | Crystal structure of 2,2′-(ethane-1,2-diyl)bis(2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines |
title_fullStr | Crystal structure of 2,2′-(ethane-1,2-diyl)bis(2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines |
title_full_unstemmed | Crystal structure of 2,2′-(ethane-1,2-diyl)bis(2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines |
title_short | Crystal structure of 2,2′-(ethane-1,2-diyl)bis(2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines |
title_sort | crystal structure of 2,2′-(ethane-1,2-diyl)bis(2,3-dihydro-1h-naphtho[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458303/ https://www.ncbi.nlm.nih.gov/pubmed/28638638 http://dx.doi.org/10.1107/S2056989017006673 |
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