Cargando…

Crystal structure of 2,2′-(ethane-1,2-di­yl)bis­(2,3-di­hydro-1H-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines

In the title compound, C(26)H(24)N(2)O(2), the oxazine moiety is fused to a naphthalene ring system. The asymmetric unit consists of one half of the mol­ecule, which lies about an inversion centre. The C atoms of the ethyl­ene spacer group adopt an anti­periplanar arrangement. The oxazine ring adopt...

Descripción completa

Detalles Bibliográficos
Autores principales: Rivera, Augusto, Cepeda-Santamaría, Juan E., Ríos-Motta, Jaime, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458303/
https://www.ncbi.nlm.nih.gov/pubmed/28638638
http://dx.doi.org/10.1107/S2056989017006673
_version_ 1783241735564951552
author Rivera, Augusto
Cepeda-Santamaría, Juan E.
Ríos-Motta, Jaime
Bolte, Michael
author_facet Rivera, Augusto
Cepeda-Santamaría, Juan E.
Ríos-Motta, Jaime
Bolte, Michael
author_sort Rivera, Augusto
collection PubMed
description In the title compound, C(26)H(24)N(2)O(2), the oxazine moiety is fused to a naphthalene ring system. The asymmetric unit consists of one half of the mol­ecule, which lies about an inversion centre. The C atoms of the ethyl­ene spacer group adopt an anti­periplanar arrangement. The oxazine ring adopts a half-chair conformation. In the crystal, supra­molecular chains running along the b axis are formed via short C—H⋯π contacts. The crystal studied was a non-merohedral twin with a fractional contribution of 0.168 (2) of the minor twin component.
format Online
Article
Text
id pubmed-5458303
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-54583032017-06-21 Crystal structure of 2,2′-(ethane-1,2-di­yl)bis­(2,3-di­hydro-1H-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines Rivera, Augusto Cepeda-Santamaría, Juan E. Ríos-Motta, Jaime Bolte, Michael Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(26)H(24)N(2)O(2), the oxazine moiety is fused to a naphthalene ring system. The asymmetric unit consists of one half of the mol­ecule, which lies about an inversion centre. The C atoms of the ethyl­ene spacer group adopt an anti­periplanar arrangement. The oxazine ring adopts a half-chair conformation. In the crystal, supra­molecular chains running along the b axis are formed via short C—H⋯π contacts. The crystal studied was a non-merohedral twin with a fractional contribution of 0.168 (2) of the minor twin component. International Union of Crystallography 2017-05-09 /pmc/articles/PMC5458303/ /pubmed/28638638 http://dx.doi.org/10.1107/S2056989017006673 Text en © Rivera et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Rivera, Augusto
Cepeda-Santamaría, Juan E.
Ríos-Motta, Jaime
Bolte, Michael
Crystal structure of 2,2′-(ethane-1,2-di­yl)bis­(2,3-di­hydro-1H-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines
title Crystal structure of 2,2′-(ethane-1,2-di­yl)bis­(2,3-di­hydro-1H-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines
title_full Crystal structure of 2,2′-(ethane-1,2-di­yl)bis­(2,3-di­hydro-1H-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines
title_fullStr Crystal structure of 2,2′-(ethane-1,2-di­yl)bis­(2,3-di­hydro-1H-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines
title_full_unstemmed Crystal structure of 2,2′-(ethane-1,2-di­yl)bis­(2,3-di­hydro-1H-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines
title_short Crystal structure of 2,2′-(ethane-1,2-di­yl)bis­(2,3-di­hydro-1H-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines
title_sort crystal structure of 2,2′-(ethane-1,2-di­yl)bis­(2,3-di­hydro-1h-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458303/
https://www.ncbi.nlm.nih.gov/pubmed/28638638
http://dx.doi.org/10.1107/S2056989017006673
work_keys_str_mv AT riveraaugusto crystalstructureof22ethane12diylbis23dihydro1hnaphtho12e13oxazineaprospectiverawmaterialforpolybenzoxazines
AT cepedasantamariajuane crystalstructureof22ethane12diylbis23dihydro1hnaphtho12e13oxazineaprospectiverawmaterialforpolybenzoxazines
AT riosmottajaime crystalstructureof22ethane12diylbis23dihydro1hnaphtho12e13oxazineaprospectiverawmaterialforpolybenzoxazines
AT boltemichael crystalstructureof22ethane12diylbis23dihydro1hnaphtho12e13oxazineaprospectiverawmaterialforpolybenzoxazines