Secondary bonding in di­methyl­bis­(morpholine-4-carbodi­thio­ato-κ(2) S,S′)tin(IV): crystal structure and Hirshfeld surface analysis

The title compound, [Sn(CH(3))(2)(C(5)H(8)NOS(2))(2)], has the Sn(IV) atom bound by two methyl groups which lie over the weaker Sn—S bonds formed by two asymmetrically chelating di­thio­carbamate ligands so that the coordination geometry is skew-trapezoidal bipyramidal. The most prominent feature of the mol­ecular packing are secondary Sn⋯S inter­actions [Sn⋯S = 3.5654 (7) Å] that lead to centrosymmetric dimers. These are connected into a three-dimensional architecture via methyl­ene-C—H⋯S and methyl-C—H⋯O(morpholino) inter­actions. The Sn⋯S inter­actions are clearly evident in the Hirshfeld surface analysis of the title compound along with a number of other inter­molecular contacts.