Crystal structure of 3-amino­pyridinium 1′-carb­oxy­ferrocene-1-carboxyl­ate

The structure of the title salt, (C(5)H(7)N(2))[Fe(C(6)H(4)O(2))(C(6)H(5)O(2))], consists of 3-amino­pyridinium cations and 1′-carb­oxy­ferrocene-1-carboxyl­ate monoanions. The ferrocenyl moiety of the anion adopts a typical sandwich structure, with Fe—C distances in the range 2.0270 (15)–2.0568 (17...

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Autores principales: Medved’ko, Aleksei V., Churakov, Andrei V., Yu, Haojie, Li, Wang, Vatsadze, Sergey Z.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458309/
https://www.ncbi.nlm.nih.gov/pubmed/28638644
http://dx.doi.org/10.1107/S2056989017007058
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author Medved’ko, Aleksei V.
Churakov, Andrei V.
Yu, Haojie
Li, Wang
Vatsadze, Sergey Z.
author_facet Medved’ko, Aleksei V.
Churakov, Andrei V.
Yu, Haojie
Li, Wang
Vatsadze, Sergey Z.
author_sort Medved’ko, Aleksei V.
collection PubMed
description The structure of the title salt, (C(5)H(7)N(2))[Fe(C(6)H(4)O(2))(C(6)H(5)O(2))], consists of 3-amino­pyridinium cations and 1′-carb­oxy­ferrocene-1-carboxyl­ate monoanions. The ferrocenyl moiety of the anion adopts a typical sandwich structure, with Fe—C distances in the range 2.0270 (15)–2.0568 (17) Å. The anion possesses an eclipsed conformation, with the torsion angle φ (C(subst)—Cp(cent)—Cp(cent)— C(subst)) equal to 66.0°. The conformations of other 1′-carb­oxy­ferrocene-1-carboxyl­ate monoanions are compared and analyzed on the basis of literature data.
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spelling pubmed-54583092017-06-21 Crystal structure of 3-amino­pyridinium 1′-carb­oxy­ferrocene-1-carboxyl­ate Medved’ko, Aleksei V. Churakov, Andrei V. Yu, Haojie Li, Wang Vatsadze, Sergey Z. Acta Crystallogr E Crystallogr Commun Research Communications The structure of the title salt, (C(5)H(7)N(2))[Fe(C(6)H(4)O(2))(C(6)H(5)O(2))], consists of 3-amino­pyridinium cations and 1′-carb­oxy­ferrocene-1-carboxyl­ate monoanions. The ferrocenyl moiety of the anion adopts a typical sandwich structure, with Fe—C distances in the range 2.0270 (15)–2.0568 (17) Å. The anion possesses an eclipsed conformation, with the torsion angle φ (C(subst)—Cp(cent)—Cp(cent)— C(subst)) equal to 66.0°. The conformations of other 1′-carb­oxy­ferrocene-1-carboxyl­ate monoanions are compared and analyzed on the basis of literature data. International Union of Crystallography 2017-05-16 /pmc/articles/PMC5458309/ /pubmed/28638644 http://dx.doi.org/10.1107/S2056989017007058 Text en © Medved'ko et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Medved’ko, Aleksei V.
Churakov, Andrei V.
Yu, Haojie
Li, Wang
Vatsadze, Sergey Z.
Crystal structure of 3-amino­pyridinium 1′-carb­oxy­ferrocene-1-carboxyl­ate
title Crystal structure of 3-amino­pyridinium 1′-carb­oxy­ferrocene-1-carboxyl­ate
title_full Crystal structure of 3-amino­pyridinium 1′-carb­oxy­ferrocene-1-carboxyl­ate
title_fullStr Crystal structure of 3-amino­pyridinium 1′-carb­oxy­ferrocene-1-carboxyl­ate
title_full_unstemmed Crystal structure of 3-amino­pyridinium 1′-carb­oxy­ferrocene-1-carboxyl­ate
title_short Crystal structure of 3-amino­pyridinium 1′-carb­oxy­ferrocene-1-carboxyl­ate
title_sort crystal structure of 3-amino­pyridinium 1′-carb­oxy­ferrocene-1-carboxyl­ate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458309/
https://www.ncbi.nlm.nih.gov/pubmed/28638644
http://dx.doi.org/10.1107/S2056989017007058
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