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Three closely related (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(meth­oxy­phen­yl)prop-2-en-1-ones]: supra­molecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π inter­actions

In the title compounds, (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(2-meth­oxy­phen­yl)prop-2-en-1-one], C(26)H(22)O(4) (I), (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(3-meth­oxy­phen­yl)prop-2-en-1-one], C(26)H(22)O(4) (II) and (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one], C(...

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Autores principales: Sim, Aijia, Chidan Kumar, C. S., Kwong, Huey Chong, Then, Li Yee, Win, Yip-Foo, Quah, Ching Kheng, Naveen, S., Chandraju, S., Lokanath, N. K., Warad, Ismail
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458319/
https://www.ncbi.nlm.nih.gov/pubmed/28638654
http://dx.doi.org/10.1107/S2056989017007460
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author Sim, Aijia
Chidan Kumar, C. S.
Kwong, Huey Chong
Then, Li Yee
Win, Yip-Foo
Quah, Ching Kheng
Naveen, S.
Chandraju, S.
Lokanath, N. K.
Warad, Ismail
author_facet Sim, Aijia
Chidan Kumar, C. S.
Kwong, Huey Chong
Then, Li Yee
Win, Yip-Foo
Quah, Ching Kheng
Naveen, S.
Chandraju, S.
Lokanath, N. K.
Warad, Ismail
author_sort Sim, Aijia
collection PubMed
description In the title compounds, (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(2-meth­oxy­phen­yl)prop-2-en-1-one], C(26)H(22)O(4) (I), (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(3-meth­oxy­phen­yl)prop-2-en-1-one], C(26)H(22)O(4) (II) and (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one], C(28)H(26)O(6) (III), the asymmetric unit consists of a half-mol­ecule, completed by crystallographic inversion symmetry. The dihedral angles between the central and terminal benzene rings are 56.98 (8), 7.74 (7) and 7.73 (7)° for (I), (II) and (III), respectively. In the crystal of (I), mol­ecules are linked by pairs of C—H⋯π inter­actions into chains running parallel to [101]. The packing for (II) and (III), features inversion dimers linked by pairs of C—H⋯O hydrogen bonds, forming R (2) (2)(16) and R (2) (2)(14) ring motifs, respectively, as parts of [201] and [101] chains, respectively.
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spelling pubmed-54583192017-06-21 Three closely related (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(meth­oxy­phen­yl)prop-2-en-1-ones]: supra­molecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π inter­actions Sim, Aijia Chidan Kumar, C. S. Kwong, Huey Chong Then, Li Yee Win, Yip-Foo Quah, Ching Kheng Naveen, S. Chandraju, S. Lokanath, N. K. Warad, Ismail Acta Crystallogr E Crystallogr Commun Research Communications In the title compounds, (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(2-meth­oxy­phen­yl)prop-2-en-1-one], C(26)H(22)O(4) (I), (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(3-meth­oxy­phen­yl)prop-2-en-1-one], C(26)H(22)O(4) (II) and (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one], C(28)H(26)O(6) (III), the asymmetric unit consists of a half-mol­ecule, completed by crystallographic inversion symmetry. The dihedral angles between the central and terminal benzene rings are 56.98 (8), 7.74 (7) and 7.73 (7)° for (I), (II) and (III), respectively. In the crystal of (I), mol­ecules are linked by pairs of C—H⋯π inter­actions into chains running parallel to [101]. The packing for (II) and (III), features inversion dimers linked by pairs of C—H⋯O hydrogen bonds, forming R (2) (2)(16) and R (2) (2)(14) ring motifs, respectively, as parts of [201] and [101] chains, respectively. International Union of Crystallography 2017-05-26 /pmc/articles/PMC5458319/ /pubmed/28638654 http://dx.doi.org/10.1107/S2056989017007460 Text en © Sim et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Sim, Aijia
Chidan Kumar, C. S.
Kwong, Huey Chong
Then, Li Yee
Win, Yip-Foo
Quah, Ching Kheng
Naveen, S.
Chandraju, S.
Lokanath, N. K.
Warad, Ismail
Three closely related (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(meth­oxy­phen­yl)prop-2-en-1-ones]: supra­molecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π inter­actions
title Three closely related (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(meth­oxy­phen­yl)prop-2-en-1-ones]: supra­molecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π inter­actions
title_full Three closely related (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(meth­oxy­phen­yl)prop-2-en-1-ones]: supra­molecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π inter­actions
title_fullStr Three closely related (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(meth­oxy­phen­yl)prop-2-en-1-ones]: supra­molecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π inter­actions
title_full_unstemmed Three closely related (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(meth­oxy­phen­yl)prop-2-en-1-ones]: supra­molecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π inter­actions
title_short Three closely related (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(meth­oxy­phen­yl)prop-2-en-1-ones]: supra­molecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π inter­actions
title_sort three closely related (2e,2′e)-3,3′-(1,4-phenyl­ene)bis­[1-(meth­oxy­phen­yl)prop-2-en-1-ones]: supra­molecular assemblies in one dimension mediated by hydrogen bonding and c—h⋯π inter­actions
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458319/
https://www.ncbi.nlm.nih.gov/pubmed/28638654
http://dx.doi.org/10.1107/S2056989017007460
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