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Three closely related (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π interactions
In the title compounds, (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(2-methoxyphenyl)prop-2-en-1-one], C(26)H(22)O(4) (I), (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(3-methoxyphenyl)prop-2-en-1-one], C(26)H(22)O(4) (II) and (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(3,4-dimethoxyphenyl)prop-2-en-1-one], C(...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458319/ https://www.ncbi.nlm.nih.gov/pubmed/28638654 http://dx.doi.org/10.1107/S2056989017007460 |
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author | Sim, Aijia Chidan Kumar, C. S. Kwong, Huey Chong Then, Li Yee Win, Yip-Foo Quah, Ching Kheng Naveen, S. Chandraju, S. Lokanath, N. K. Warad, Ismail |
author_facet | Sim, Aijia Chidan Kumar, C. S. Kwong, Huey Chong Then, Li Yee Win, Yip-Foo Quah, Ching Kheng Naveen, S. Chandraju, S. Lokanath, N. K. Warad, Ismail |
author_sort | Sim, Aijia |
collection | PubMed |
description | In the title compounds, (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(2-methoxyphenyl)prop-2-en-1-one], C(26)H(22)O(4) (I), (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(3-methoxyphenyl)prop-2-en-1-one], C(26)H(22)O(4) (II) and (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(3,4-dimethoxyphenyl)prop-2-en-1-one], C(28)H(26)O(6) (III), the asymmetric unit consists of a half-molecule, completed by crystallographic inversion symmetry. The dihedral angles between the central and terminal benzene rings are 56.98 (8), 7.74 (7) and 7.73 (7)° for (I), (II) and (III), respectively. In the crystal of (I), molecules are linked by pairs of C—H⋯π interactions into chains running parallel to [101]. The packing for (II) and (III), features inversion dimers linked by pairs of C—H⋯O hydrogen bonds, forming R (2) (2)(16) and R (2) (2)(14) ring motifs, respectively, as parts of [201] and [101] chains, respectively. |
format | Online Article Text |
id | pubmed-5458319 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-54583192017-06-21 Three closely related (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π interactions Sim, Aijia Chidan Kumar, C. S. Kwong, Huey Chong Then, Li Yee Win, Yip-Foo Quah, Ching Kheng Naveen, S. Chandraju, S. Lokanath, N. K. Warad, Ismail Acta Crystallogr E Crystallogr Commun Research Communications In the title compounds, (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(2-methoxyphenyl)prop-2-en-1-one], C(26)H(22)O(4) (I), (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(3-methoxyphenyl)prop-2-en-1-one], C(26)H(22)O(4) (II) and (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(3,4-dimethoxyphenyl)prop-2-en-1-one], C(28)H(26)O(6) (III), the asymmetric unit consists of a half-molecule, completed by crystallographic inversion symmetry. The dihedral angles between the central and terminal benzene rings are 56.98 (8), 7.74 (7) and 7.73 (7)° for (I), (II) and (III), respectively. In the crystal of (I), molecules are linked by pairs of C—H⋯π interactions into chains running parallel to [101]. The packing for (II) and (III), features inversion dimers linked by pairs of C—H⋯O hydrogen bonds, forming R (2) (2)(16) and R (2) (2)(14) ring motifs, respectively, as parts of [201] and [101] chains, respectively. International Union of Crystallography 2017-05-26 /pmc/articles/PMC5458319/ /pubmed/28638654 http://dx.doi.org/10.1107/S2056989017007460 Text en © Sim et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Sim, Aijia Chidan Kumar, C. S. Kwong, Huey Chong Then, Li Yee Win, Yip-Foo Quah, Ching Kheng Naveen, S. Chandraju, S. Lokanath, N. K. Warad, Ismail Three closely related (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π interactions |
title | Three closely related (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π interactions |
title_full | Three closely related (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π interactions |
title_fullStr | Three closely related (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π interactions |
title_full_unstemmed | Three closely related (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π interactions |
title_short | Three closely related (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and C—H⋯π interactions |
title_sort | three closely related (2e,2′e)-3,3′-(1,4-phenylene)bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and c—h⋯π interactions |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458319/ https://www.ncbi.nlm.nih.gov/pubmed/28638654 http://dx.doi.org/10.1107/S2056989017007460 |
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