Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion

A highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion to afford cyclohexenes has been developed. It was shown that the assisting olefin moiety was indispensable for the formation of the cyclohexene product. Furthermore, preliminary studies on c...

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Detalles Bibliográficos
Autores principales: Qiu, Youai, Yang, Bin, Zhu, Can, Bäckvall, Jan-E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458679/
https://www.ncbi.nlm.nih.gov/pubmed/28616136
http://dx.doi.org/10.1039/c6sc02660e
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author Qiu, Youai
Yang, Bin
Zhu, Can
Bäckvall, Jan-E.
author_facet Qiu, Youai
Yang, Bin
Zhu, Can
Bäckvall, Jan-E.
author_sort Qiu, Youai
collection PubMed
description A highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion to afford cyclohexenes has been developed. It was shown that the assisting olefin moiety was indispensable for the formation of the cyclohexene product. Furthermore, preliminary studies on chiral anion-induced asymmetrical carbocyclization–borylation of enallenes have been carried out.
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spelling pubmed-54586792017-06-14 Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion Qiu, Youai Yang, Bin Zhu, Can Bäckvall, Jan-E. Chem Sci Chemistry A highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion to afford cyclohexenes has been developed. It was shown that the assisting olefin moiety was indispensable for the formation of the cyclohexene product. Furthermore, preliminary studies on chiral anion-induced asymmetrical carbocyclization–borylation of enallenes have been carried out. Royal Society of Chemistry 2017-01-01 2016-09-15 /pmc/articles/PMC5458679/ /pubmed/28616136 http://dx.doi.org/10.1039/c6sc02660e Text en This journal is © The Royal Society of Chemistry 2016 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Qiu, Youai
Yang, Bin
Zhu, Can
Bäckvall, Jan-E.
Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion
title Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion
title_full Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion
title_fullStr Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion
title_full_unstemmed Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion
title_short Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion
title_sort highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458679/
https://www.ncbi.nlm.nih.gov/pubmed/28616136
http://dx.doi.org/10.1039/c6sc02660e
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