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Pressure induced polymerization of acetylide anions in CaC(2) and 10(7) fold enhancement of electrical conductivity
Transformation between different types of carbon–carbon bonding in carbides often results in a dramatic change of physical and chemical properties. Under external pressure, unsaturated carbon atoms form new covalent bonds regardless of the electrostatic repulsion. It was predicted that calcium acety...
| Autores principales: | , , , , , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458717/ https://www.ncbi.nlm.nih.gov/pubmed/28616132 http://dx.doi.org/10.1039/c6sc02830f |