1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes

A convenient methodology for the highly stereoselective synthesis of unsymmetrical (1E,3E)-1,4-disubstituted 1,3-dienes based on palladium-catalyzed Hiyama cross-coupling reaction of 1-(triethoxysilyl)-substituted buta-1,3-dienes with aryl iodides is reported.

Detalles Bibliográficos
Autores principales: Szudkowska-Frątczak, Justyna, Taczała, Mariusz, Pawluć, Piotr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458880/
https://www.ncbi.nlm.nih.gov/pubmed/28793635
http://dx.doi.org/10.3390/ma8115378
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author Szudkowska-Frątczak, Justyna
Taczała, Mariusz
Pawluć, Piotr
author_facet Szudkowska-Frątczak, Justyna
Taczała, Mariusz
Pawluć, Piotr
author_sort Szudkowska-Frątczak, Justyna
collection PubMed
description A convenient methodology for the highly stereoselective synthesis of unsymmetrical (1E,3E)-1,4-disubstituted 1,3-dienes based on palladium-catalyzed Hiyama cross-coupling reaction of 1-(triethoxysilyl)-substituted buta-1,3-dienes with aryl iodides is reported.
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spelling pubmed-54588802017-07-28 1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes Szudkowska-Frątczak, Justyna Taczała, Mariusz Pawluć, Piotr Materials (Basel) Communication A convenient methodology for the highly stereoselective synthesis of unsymmetrical (1E,3E)-1,4-disubstituted 1,3-dienes based on palladium-catalyzed Hiyama cross-coupling reaction of 1-(triethoxysilyl)-substituted buta-1,3-dienes with aryl iodides is reported. MDPI 2015-10-28 /pmc/articles/PMC5458880/ /pubmed/28793635 http://dx.doi.org/10.3390/ma8115378 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Szudkowska-Frątczak, Justyna
Taczała, Mariusz
Pawluć, Piotr
1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes
title 1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes
title_full 1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes
title_fullStr 1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes
title_full_unstemmed 1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes
title_short 1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes
title_sort 1-(triethoxysilyl)buta-1,3-dienes—new building blocks for stereoselective synthesis of unsymmetrical (e,e)-1,4-disubstituted 1,3-dienes
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458880/
https://www.ncbi.nlm.nih.gov/pubmed/28793635
http://dx.doi.org/10.3390/ma8115378
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