Ligand manipulation of charge transfer excited state relaxation and spin crossover in [Fe(2,2′-bipyridine)(2)(CN)(2)]

We have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize the electronic excited state dynamics of [Fe(bpy)(2)(CN)(2)], where bpy=2,2′-bipyridine, initiated by metal-to-ligand charge transfer (MLCT) excitation. The excited-state absorption in the transient UV-...

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Detalles Bibliográficos
Autores principales: Kjær, Kasper S., Zhang, Wenkai, Alonso-Mori, Roberto, Bergmann, Uwe, Chollet, Matthieu, Hadt, Ryan G., Hartsock, Robert W., Harlang, Tobias, Kroll, Thomas, Kubiček, Katharina, Lemke, Henrik T., Liang, Huiyang W., Liu, Yizhu, Nielsen, Martin M., Robinson, Joseph S., Solomon, Edward I., Sokaras, Dimosthenis, van Driel, Tim B., Weng, Tsu-Chien, Zhu, Diling, Persson, Petter, Wärnmark, Kenneth, Sundström, Villy, Gaffney, Kelly J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Crystallographic Association 2017
Materias:
Ultrafast Structural Dynamics—A Tribute to Ahmed H. Zewail
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5461172/
https://www.ncbi.nlm.nih.gov/pubmed/28653021
http://dx.doi.org/10.1063/1.4985017

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