New coordination features; a bridging pyridine and the forced shortest non-covalent distance between two CO(3) (2–) species

The aerobic reaction of the multidentate ligand 2,6-bis-(3-oxo-3-(2-hydroxyphenyl)-propionyl)-pyridine, H(4)L, with Co(ii) salts in strong basic conditions produces the clusters [Co(4)(L)(2)(OH)(py)(7)]NO(3) (1) and [Co(8)Na(4)(L)(4)(OH)(2)(CO(3))(2)(py)(10)](BF(4))(2) (2). Analysis of their structu...

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Detalles Bibliográficos
Autores principales: Velasco, V., Aguilà, D., Barrios, L. A., Borilovic, I., Roubeau, O., Ribas-Ariño, J., Fumanal, M., Teat, S. J., Aromí, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5461881/
https://www.ncbi.nlm.nih.gov/pubmed/28616127
http://dx.doi.org/10.1039/c4sc02491e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5461881/
https://www.ncbi.nlm.nih.gov/pubmed/28616127
http://dx.doi.org/10.1039/c4sc02491e

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