Cargando…

Enantioselective decarboxylative chlorination of β-ketocarboxylic acids

Stereoselective halogenation is a highly useful organic transformation for multistep syntheses because the resulting chiral organohalides can serve as precursors for various medicinally relevant derivatives. Even though decarboxylative halogenation of aliphatic carboxylic acids is a useful and funda...

Descripción completa

Detalles Bibliográficos
Autores principales:	Shibatomi, Kazutaka, Kitahara, Kazumasa, Sasaki, Nozomi, Kawasaki, Yohei, Fujisawa, Ikuhide, Iwasa, Seiji
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group 2017
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5465354/ https://www.ncbi.nlm.nih.gov/pubmed/28580951 http://dx.doi.org/10.1038/ncomms15600

Ejemplares similares

Amine-Catalyzed Decarboxylative Aldol Reaction of β-Ketocarboxylic Acids with Trifluoropyruvates
por: Kawanishi, Ryouta, et al.
Publicado: (2019)

Asymmetric Synthesis of Tertiary α -Hydroxyketones by Enantioselective Decarboxylative Chlorination and Subsequent Nucleophilic Substitution
por: Kam, Mei Kee, et al.
Publicado: (2020)

Enantioselective fluorination of α-branched aldehydes and subsequent conversion to α-hydroxyacetals via stereospecific C–F bond cleavage
por: Shibatomi, Kazutaka, et al.
Publicado: (2016)

Decarboxylative aldol reaction of α,α-difluoro-β-ketocarboxylate salt: a facile method for generation of difluoroenolate
por: Tarui, Atsushi, et al.
Publicado: (2018)

Decarboxylative trifluoromethylthiolation of pyridylacetates
por: Kawanishi, Ryouta, et al.
Publicado: (2021)

Ligand Exchange Reaction on a Ru(II)–Pheox Complex as a Mechanistic Study of Catalytic Reactions
por: Nakagawa, Yoko, et al.
Publicado: (2018)

Highly stereoselective spirocyclopropanation of various diazooxindoles with olefins catalyzed using Ru(ii)-complex
por: Tone, Masaya, et al.
Publicado: (2018)

Reusable and highly enantioselective water-soluble Ru(II)-Amm-Pheox catalyst for intramolecular cyclopropanation of diazo compounds
por: Mandour, Hamada S A, et al.
Publicado: (2019)

Enzymatic Enantioselective Decarboxylative Protonation of Heteroaryl Malonates
por: Lewin, Ross, et al.
Publicado: (2015)

Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones
por: Craig, Robert A., et al.
Publicado: (2015)

Enantioselective, Decarboxylative (3+2)-Cycloaddition of Azomethine Ylides and Chromone-3-Carboxylic Acids
por: Kowalska, Ewelina, et al.
Publicado: (2022)

A convenient enantioselective decarboxylative aldol reaction to access chiral α-hydroxy esters using β-keto acids
por: Duan, Zhiqiang, et al.
Publicado: (2014)

Organocatalytic asymmetric fluorination of α-chloroaldehydes involving kinetic resolution
por: Shibatomi, Kazutaka, et al.
Publicado: (2014)

Cu-catalyzed enantioselective decarboxylative cyanation via the synergistic merger of photocatalysis and electrochemistry
por: Yuan, Yin, et al.
Publicado: (2022)

Enantioselective Construction of Quaternary N-Heterocycles by Palladium-Catalyzed Decarboxylative Allylic Alkylation of Lactams
por: Behenna, Douglas C., et al.
Publicado: (2011)

Catalytic enantioselective synthesis of carbocyclic and heterocyclic spiranes via a decarboxylative aldol cyclization
por: Inanaga, Kazato, et al.
Publicado: (2020)

Origins of Enhanced Enantioselectivity in the Pd-Catalyzed Decarboxylative Allylic Alkylation of N-Benzoyl Lactams ()
por: Cusumano, Alexander Q., et al.
Publicado: (2023)

Enantioselective Synthesis of Chromanones Bearing an α,α-Disubstituted α-Amino Acid Moiety via Decarboxylative Michael Reaction
por: Bojanowski, Jan, et al.
Publicado: (2019)

Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation
por: Sun, Alexander W., et al.
Publicado: (2018)

Regio‐, Diastereo‐, and Enantioselective Decarboxylative Hydroaminoalkylation of Dienol Ethers Enabled by Dual Palladium/Photoredox Catalysis
por: Zheng, Jun, et al.
Publicado: (2022)

Iridium-Catalyzed Enantioselective Alkene Hydroalkylation via a Heteroaryl-Directed Enolization–Decarboxylation Sequence
por: Jing, Changcheng, et al.
Publicado: (2023)

Decarboxylative Hydroxylation of Benzoic Acids
por: Su, Wanqi, et al.
Publicado: (2021)

Decarboxylative Polyfluoroarylation of Alkylcarboxylic Acids
por: Sun, Xiang, et al.
Publicado: (2021)

Structural Study on Hypochlorous Acid-Mediated Chlorination of Betanin and Its Decarboxylated Derivatives from an Anti-Inflammatory Beta vulgaris L. Extract
por: Kumorkiewicz-Jamro, Agnieszka, et al.
Publicado: (2020)

Mechanistically Guided Design of an Efficient and Enantioselective Aminocatalytic α-Chlorination of Aldehydes
por: Hutchinson, George, et al.
Publicado: (2021)

Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates
por: Alexy, Eric J., et al.
Publicado: (2019)

Decarboxylative Alkenylation
por: Edwards, Jacob T., et al.
Publicado: (2017)

Light‐Driven Enzymatic Decarboxylation of Fatty Acids
por: Huijbers, Mieke M. E., et al.
Publicado: (2018)

Oxidative Decarboxylation of Levulinic Acid by Cupric Oxides
por: Gong, Yan, et al.
Publicado: (2010)

Light‐Driven Enzymatic Decarboxylation of Dicarboxylic Acids
por: Zeng, Yong‐Yi, et al.
Publicado: (2021)

Kinetics and thermodynamics of enzymatic decarboxylation of α,β-unsaturated acid: a theoretical study
por: Promma, Phorntep, et al.
Publicado: (2022)

Development of copper-catalyzed enantioselective decarboxylative aldolization for the preparation of perfluorinated 1,3,5-triols featuring supramolecular recognition properties
por: Sperandio, Céline, et al.
Publicado: (2019)

Decarboxylative Annulation of α-Amino Acids with γ-Nitroaldehydes
por: Kang, YoungKu, et al.
Publicado: (2016)

Hydrocarbon Synthesis via Photoenzymatic Decarboxylation of Carboxylic Acids
por: Zhang, Wuyuan, et al.
Publicado: (2019)

Oxidative Decarboxylation of Levulinic Acid by Silver(I)/Persulfate
por: Gong, Yan, et al.
Publicado: (2011)

Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis
por: Yatham, Veera Reddy, et al.
Publicado: (2019)

Intensification of Photobiocatalytic Decarboxylation of Fatty Acids for the Production of Biodiesel
por: Duong, Hong T., et al.
Publicado: (2021)

Chemoenzymatic Hunsdiecker-Type Decarboxylative Bromination of Cinnamic Acids
por: Li, Huanhuan, et al.
Publicado: (2022)

A highly selective decarboxylative deuteration of carboxylic acids
por: Li, Nian, et al.
Publicado: (2021)

Copper-Catalyzed Decarboxylative Elimination of Carboxylic Acids to Styrenes
por: Stanton, Michael P., et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_rsq0rip9gqiqbgprkalnjk02pe