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Scalable, Electrochemical Oxidation of Unactivated C–H Bonds

[Image: see text] A practical electrochemical oxidation of unactivated C–H bonds is presented. This reaction utilizes a simple redox mediator, quinuclidine, with inexpensive carbon and nickel electrodes to selectively functionalize “deep-seated” methylene and methine moieties. The process exhibits a...

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Detalles Bibliográficos
Autores principales:	Kawamata, Yu, Yan, Ming, Liu, Zhiqing, Bao, Deng-Hui, Chen, Jinshan, Starr, Jeremy T., Baran, Phil S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5465511/ https://www.ncbi.nlm.nih.gov/pubmed/28510449 http://dx.doi.org/10.1021/jacs.7b03539

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