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Additive Enhanced Creeping of Sodium Chloride Crystals

[Image: see text] This article investigates the mechanism behind the creeping of sodium chloride induced by additives. Here, an experimental approach is complemented with theoretical considerations to describe how creeping patterns of brine evolve and how the introduction of additives into the solut...

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Autores principales: Townsend, Eleanor R., van Enckevort, Willem J. P., Meijer, Jan A. M., Vlieg, Elias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5465512/
https://www.ncbi.nlm.nih.gov/pubmed/28615995
http://dx.doi.org/10.1021/acs.cgd.7b00023
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author Townsend, Eleanor R.
van Enckevort, Willem J. P.
Meijer, Jan A. M.
Vlieg, Elias
author_facet Townsend, Eleanor R.
van Enckevort, Willem J. P.
Meijer, Jan A. M.
Vlieg, Elias
author_sort Townsend, Eleanor R.
collection PubMed
description [Image: see text] This article investigates the mechanism behind the creeping of sodium chloride induced by additives. Here, an experimental approach is complemented with theoretical considerations to describe how creeping patterns of brine evolve and how the introduction of additives into the solution affects the morphology of the resultant crystals. We have found that these additives cause kinetic roughening and morphological instability mainly due to the reduction of surface free energy. There was also a marked increase in three-dimensional nucleation of the NaCl crystals and thus branching.
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spelling pubmed-54655122017-06-12 Additive Enhanced Creeping of Sodium Chloride Crystals Townsend, Eleanor R. van Enckevort, Willem J. P. Meijer, Jan A. M. Vlieg, Elias Cryst Growth Des [Image: see text] This article investigates the mechanism behind the creeping of sodium chloride induced by additives. Here, an experimental approach is complemented with theoretical considerations to describe how creeping patterns of brine evolve and how the introduction of additives into the solution affects the morphology of the resultant crystals. We have found that these additives cause kinetic roughening and morphological instability mainly due to the reduction of surface free energy. There was also a marked increase in three-dimensional nucleation of the NaCl crystals and thus branching. American Chemical Society 2017-04-26 2017-06-07 /pmc/articles/PMC5465512/ /pubmed/28615995 http://dx.doi.org/10.1021/acs.cgd.7b00023 Text en Copyright © 2017 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Townsend, Eleanor R.
van Enckevort, Willem J. P.
Meijer, Jan A. M.
Vlieg, Elias
Additive Enhanced Creeping of Sodium Chloride Crystals
title Additive Enhanced Creeping of Sodium Chloride Crystals
title_full Additive Enhanced Creeping of Sodium Chloride Crystals
title_fullStr Additive Enhanced Creeping of Sodium Chloride Crystals
title_full_unstemmed Additive Enhanced Creeping of Sodium Chloride Crystals
title_short Additive Enhanced Creeping of Sodium Chloride Crystals
title_sort additive enhanced creeping of sodium chloride crystals
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5465512/
https://www.ncbi.nlm.nih.gov/pubmed/28615995
http://dx.doi.org/10.1021/acs.cgd.7b00023
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