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On the impact of Vertical Alignment of MoS(2) for Efficient Lithium Storage
Herein, we report energy storage devices, which are based on densely packed, vertically aligned MoS(2) (VA-MoS(2)) or planar oriented MoS(2) (PO-MoS(2)) and compare their electrochemical performances. The VA-MoS(2) films have been processed by chemical vapor deposition (CVD) to reach unprecedented m...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5468230/ https://www.ncbi.nlm.nih.gov/pubmed/28607367 http://dx.doi.org/10.1038/s41598-017-03453-x |
Sumario: | Herein, we report energy storage devices, which are based on densely packed, vertically aligned MoS(2) (VA-MoS(2)) or planar oriented MoS(2) (PO-MoS(2)) and compare their electrochemical performances. The VA-MoS(2) films have been processed by chemical vapor deposition (CVD) to reach unprecedented micron-scale thick films while maintaining the vertical alignment for the whole thickness. The VA-MoS(2) and the PO-MoS(2) films form a high-performance Li-ion electrode, reaching the theoretical limits of reversible capacity for this material (800 mAh/g; twice the specific capacity of graphite). The vertical alignment allows faster charge-discharge rates while maintaining a high specific capacity (C-rate measurements). Noteworthy, the reversible cycling of the Li-ion electrode also benefits from the vertical alignment. In this article, we present the full synthesis, structural and electrochemical characterization of VA-MoS(2) along with the properties of PO-MoS(2) to deconvolute the intrinsic properties of MoS(2) from the influence of the layers’ orientation. |
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