Construction of SnO(2)−Graphene Composite with Half-Supported Cluster Structure as Anode toward Superior Lithium Storage Properties

Inspired by nature, herein we designed a novel construction of SnO(2) anodes with an extremely high lithium storage performance. By utilizing small sheets of graphene oxide, the partitioned-pomegranate-like structure was constructed (SnO(2)@C@half-rGO), in which the porous clusters of SnO(2) nanoparticles are partially supported by reduced graphene oxide sheets while the rest part is exposed (half-supported), like partitioned pomegranates. When served as anode for lithium-ion batteries, SnO(2)@C@half-rGO exhibited considerably high specific capacity (1034.5 mAh g(−1) after 200 cycles at 100 mA g(−1)), superior rate performance and remarkable durability (370.3 mAh g(−1) after 10000 cycles at 5 A g(−1)). When coupled with graphitized porous carbon cathode for lithium-ion hybrid capacitors, the fabricated devices delivered a high energy density of 257 Wh kg(−1) at ∼200 W kg(−1) and maintained 79 Wh kg(−1) at a super-high power density of ∼20 kW kg(−1) within a wide voltage window up to 4 V. This facile and scalable approach demonstrates a new architecture for graphene-based composite for practical use in energy storage with high performance.