Cargando…

(BEDT‐TTF)(2)Cu(2)(HCOO)(5): An Organic–Inorganic Hybrid Conducting Magnet

This month's cover picture results from Professor Bin Zhang's collaborative work between Chinese Academy of Sciences and Peking University (China). Since the discovery of high‐temperature superconductors for hole doping on parent antiferromagnetic compound La(2)CuO(4), the antiferromagneti...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Bin, Zhang, Yan, Wang, Zheming, Gao, Zengqiang, Yang, Deliang, Wang, Dongwei, Guo, Yanjun, Zhu, Daoben
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5474650/
https://www.ncbi.nlm.nih.gov/pubmed/28638757
http://dx.doi.org/10.1002/open.201700089
_version_ 1783244490122723328
author Zhang, Bin
Zhang, Yan
Wang, Zheming
Gao, Zengqiang
Yang, Deliang
Wang, Dongwei
Guo, Yanjun
Zhu, Daoben
author_facet Zhang, Bin
Zhang, Yan
Wang, Zheming
Gao, Zengqiang
Yang, Deliang
Wang, Dongwei
Guo, Yanjun
Zhu, Daoben
author_sort Zhang, Bin
collection PubMed
description This month's cover picture results from Professor Bin Zhang's collaborative work between Chinese Academy of Sciences and Peking University (China). Since the discovery of high‐temperature superconductors for hole doping on parent antiferromagnetic compound La(2)CuO(4), the antiferromagnetic molecular crystal with a (4,4) grid copper‐formate framework Cu(HCOO)(2)(H(2)O)(4) and its deuterated compound (Cu(DCOO)(2)(D(2)O)(4)) have been studied extensively for supposed dual‐functional molecular crystals. The cover picture shows the ideal situation by replacing intercalated H(2)O with an organic donor. The organic–inorganic hybrid (BEDT‐TTF)(2)Cu(2)(HCOO)(5) is obtained through the electrochemical oxidation of neutral BEDT‐TTF in the presence of an ammonium salt of the 1D copper‐formate framework [(C(2)H(5))(3)NH](2)Cu(2)(HCOO)(5) in a C(6)H(5)Cl‐C(2)H(5)OH solution. For more details, read the full text of the Communication at 10.1002/open.201700041.
format Online
Article
Text
id pubmed-5474650
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-54746502017-06-21 (BEDT‐TTF)(2)Cu(2)(HCOO)(5): An Organic–Inorganic Hybrid Conducting Magnet Zhang, Bin Zhang, Yan Wang, Zheming Gao, Zengqiang Yang, Deliang Wang, Dongwei Guo, Yanjun Zhu, Daoben ChemistryOpen Cover Profile This month's cover picture results from Professor Bin Zhang's collaborative work between Chinese Academy of Sciences and Peking University (China). Since the discovery of high‐temperature superconductors for hole doping on parent antiferromagnetic compound La(2)CuO(4), the antiferromagnetic molecular crystal with a (4,4) grid copper‐formate framework Cu(HCOO)(2)(H(2)O)(4) and its deuterated compound (Cu(DCOO)(2)(D(2)O)(4)) have been studied extensively for supposed dual‐functional molecular crystals. The cover picture shows the ideal situation by replacing intercalated H(2)O with an organic donor. The organic–inorganic hybrid (BEDT‐TTF)(2)Cu(2)(HCOO)(5) is obtained through the electrochemical oxidation of neutral BEDT‐TTF in the presence of an ammonium salt of the 1D copper‐formate framework [(C(2)H(5))(3)NH](2)Cu(2)(HCOO)(5) in a C(6)H(5)Cl‐C(2)H(5)OH solution. For more details, read the full text of the Communication at 10.1002/open.201700041. John Wiley and Sons Inc. 2017-05-31 /pmc/articles/PMC5474650/ /pubmed/28638757 http://dx.doi.org/10.1002/open.201700089 Text en © 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
spellingShingle Cover Profile
Zhang, Bin
Zhang, Yan
Wang, Zheming
Gao, Zengqiang
Yang, Deliang
Wang, Dongwei
Guo, Yanjun
Zhu, Daoben
(BEDT‐TTF)(2)Cu(2)(HCOO)(5): An Organic–Inorganic Hybrid Conducting Magnet
title (BEDT‐TTF)(2)Cu(2)(HCOO)(5): An Organic–Inorganic Hybrid Conducting Magnet
title_full (BEDT‐TTF)(2)Cu(2)(HCOO)(5): An Organic–Inorganic Hybrid Conducting Magnet
title_fullStr (BEDT‐TTF)(2)Cu(2)(HCOO)(5): An Organic–Inorganic Hybrid Conducting Magnet
title_full_unstemmed (BEDT‐TTF)(2)Cu(2)(HCOO)(5): An Organic–Inorganic Hybrid Conducting Magnet
title_short (BEDT‐TTF)(2)Cu(2)(HCOO)(5): An Organic–Inorganic Hybrid Conducting Magnet
title_sort (bedt‐ttf)(2)cu(2)(hcoo)(5): an organic–inorganic hybrid conducting magnet
topic Cover Profile
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5474650/
https://www.ncbi.nlm.nih.gov/pubmed/28638757
http://dx.doi.org/10.1002/open.201700089
work_keys_str_mv AT zhangbin bedtttf2cu2hcoo5anorganicinorganichybridconductingmagnet
AT zhangyan bedtttf2cu2hcoo5anorganicinorganichybridconductingmagnet
AT wangzheming bedtttf2cu2hcoo5anorganicinorganichybridconductingmagnet
AT gaozengqiang bedtttf2cu2hcoo5anorganicinorganichybridconductingmagnet
AT yangdeliang bedtttf2cu2hcoo5anorganicinorganichybridconductingmagnet
AT wangdongwei bedtttf2cu2hcoo5anorganicinorganichybridconductingmagnet
AT guoyanjun bedtttf2cu2hcoo5anorganicinorganichybridconductingmagnet
AT zhudaoben bedtttf2cu2hcoo5anorganicinorganichybridconductingmagnet