Convenient and General Zinc‐Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions

A convenient and general zinc‐catalyzed borylation of aryl diazonium salts and aryltriazenes has been developed. With bis‐ (pinacolato)diboron as the borylation reagent, aryldiazonium tetrafluoroborate salts and aryltriazenes were transformed into the corresponding arylboronates in moderate to excel...

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Autores principales: Qi, Xinxin, Jiang, Li‐Bing, Zhou, Chao, Peng, Jin‐Bao, Wu, Xiao‐Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5474665/
https://www.ncbi.nlm.nih.gov/pubmed/28638765
http://dx.doi.org/10.1002/open.201700036
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author Qi, Xinxin
Jiang, Li‐Bing
Zhou, Chao
Peng, Jin‐Bao
Wu, Xiao‐Feng
author_facet Qi, Xinxin
Jiang, Li‐Bing
Zhou, Chao
Peng, Jin‐Bao
Wu, Xiao‐Feng
author_sort Qi, Xinxin
collection PubMed
description A convenient and general zinc‐catalyzed borylation of aryl diazonium salts and aryltriazenes has been developed. With bis‐ (pinacolato)diboron as the borylation reagent, aryldiazonium tetrafluoroborate salts and aryltriazenes were transformed into the corresponding arylboronates in moderate to excellent yields under mild conditions. As a convenient and practical methodology, no additional ligands, base, or any other additives are required here.
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spelling pubmed-54746652017-06-21 Convenient and General Zinc‐Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions Qi, Xinxin Jiang, Li‐Bing Zhou, Chao Peng, Jin‐Bao Wu, Xiao‐Feng ChemistryOpen Communications A convenient and general zinc‐catalyzed borylation of aryl diazonium salts and aryltriazenes has been developed. With bis‐ (pinacolato)diboron as the borylation reagent, aryldiazonium tetrafluoroborate salts and aryltriazenes were transformed into the corresponding arylboronates in moderate to excellent yields under mild conditions. As a convenient and practical methodology, no additional ligands, base, or any other additives are required here. John Wiley and Sons Inc. 2017-03-16 /pmc/articles/PMC5474665/ /pubmed/28638765 http://dx.doi.org/10.1002/open.201700036 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs (http://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Qi, Xinxin
Jiang, Li‐Bing
Zhou, Chao
Peng, Jin‐Bao
Wu, Xiao‐Feng
Convenient and General Zinc‐Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions
title Convenient and General Zinc‐Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions
title_full Convenient and General Zinc‐Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions
title_fullStr Convenient and General Zinc‐Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions
title_full_unstemmed Convenient and General Zinc‐Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions
title_short Convenient and General Zinc‐Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions
title_sort convenient and general zinc‐catalyzed borylation of aryl diazonium salts and aryltriazenes under mild conditions
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5474665/
https://www.ncbi.nlm.nih.gov/pubmed/28638765
http://dx.doi.org/10.1002/open.201700036
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