A pendant proton shuttle on [Fe(4)N(CO)(12)](–) alters product selectivity in formate vs. H(2) production via the hydride [H–Fe(4)N(CO)(12)](–)

Proton relays are known to increase reaction rates for H(2) evolution and lower overpotentials in electrocatalytic reactions. In this report we describe two electrocatalysts, [Fe(4)N(CO)(11)(PPh(3))](–) (1(–)) which has no proton relay, and hydroxyl-containing [Fe(4)N(CO)(11)(Ph(2)P(CH(2))(2)OH)](–)...

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Detalles Bibliográficos
Autores principales: Loewen, Natalia D., Thompson, Emily J., Kagan, Michael, Banales, Carolina L., Myers, Thomas W., Fettinger, James C., Berben, Louise A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477009/
https://www.ncbi.nlm.nih.gov/pubmed/28660048
http://dx.doi.org/10.1039/c5sc03169a

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