Stereoselective synthesis of protected l- and d-dideoxysugars and analogues via Prins cyclisations

A de novo approach for the rapid construction of orthogonally protected l- and d-deoxysugars and analogues is described. A novel and robust silicon-acetal undergoes Prins cyclisations with a series of homoallylic alcohols in high yield and excellent stereocontrol. Modified Tamao–Fleming oxidation of...

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Detalles Bibliográficos
Autores principales: Beattie, Ryan J., Hornsby, Thomas W., Craig, Gemma, Galan, M. Carmen, Willis, Christine L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477037/
https://www.ncbi.nlm.nih.gov/pubmed/28660050
http://dx.doi.org/10.1039/c5sc04144a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477037/
https://www.ncbi.nlm.nih.gov/pubmed/28660050
http://dx.doi.org/10.1039/c5sc04144a

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