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Spin-crossover and high-spin iron(ii) complexes as chemical shift (19)F magnetic resonance thermometers
The potential utility of paramagnetic transition metal complexes as chemical shift (19)F magnetic resonance (MR) thermometers is demonstrated. Further, spin-crossover Fe(II) complexes are shown to provide much higher temperature sensitivity than do the high-spin analogues, owing to the variation of...
Autores principales: | Thorarinsdottir, Agnes E., Gaudette, Alexandra I., Harris, T. David |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477811/ https://www.ncbi.nlm.nih.gov/pubmed/28694955 http://dx.doi.org/10.1039/c6sc04287b |
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