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Enhanced intersystem crossing in core-twisted aromatics

We describe the design, bottom-up synthesis and X-ray single crystal structure of systematically twisted aromatics 1c and 2d for efficient intersystem crossing. Steric congestion at the cove region creates a nonplanar geometry that induces a significant yield of triplet excited states in the electro...

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Detalles Bibliográficos
Autores principales:	Nagarajan, Kalaivanan, Mallia, Ajith R., Muraleedharan, Keerthi, Hariharan, Mahesh
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477835/ https://www.ncbi.nlm.nih.gov/pubmed/28694952 http://dx.doi.org/10.1039/c6sc05126j

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