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Elastically driven intermittent microscopic dynamics in soft solids
Soft solids with tunable mechanical response are at the core of new material technologies, but a crucial limit for applications is their progressive aging over time, which dramatically affects their functionalities. The generally accepted paradigm is that such aging is gradual and its origin is in s...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5482056/ https://www.ncbi.nlm.nih.gov/pubmed/28635964 http://dx.doi.org/10.1038/ncomms15846 |
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author | Bouzid, Mehdi Colombo, Jader Barbosa, Lucas Vieira Del Gado, Emanuela |
author_facet | Bouzid, Mehdi Colombo, Jader Barbosa, Lucas Vieira Del Gado, Emanuela |
author_sort | Bouzid, Mehdi |
collection | PubMed |
description | Soft solids with tunable mechanical response are at the core of new material technologies, but a crucial limit for applications is their progressive aging over time, which dramatically affects their functionalities. The generally accepted paradigm is that such aging is gradual and its origin is in slower than exponential microscopic dynamics, akin to the ones in supercooled liquids or glasses. Nevertheless, time- and space-resolved measurements have provided contrasting evidence: dynamics faster than exponential, intermittency and abrupt structural changes. Here we use 3D computer simulations of a microscopic model to reveal that the timescales governing stress relaxation, respectively, through thermal fluctuations and elastic recovery are key for the aging dynamics. When thermal fluctuations are too weak, stress heterogeneities frozen-in upon solidification can still partially relax through elastically driven fluctuations. Such fluctuations are intermittent, because of strong correlations that persist over the timescale of experiments or simulations, leading to faster than exponential dynamics. |
format | Online Article Text |
id | pubmed-5482056 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | Nature Publishing Group |
record_format | MEDLINE/PubMed |
spelling | pubmed-54820562017-07-06 Elastically driven intermittent microscopic dynamics in soft solids Bouzid, Mehdi Colombo, Jader Barbosa, Lucas Vieira Del Gado, Emanuela Nat Commun Article Soft solids with tunable mechanical response are at the core of new material technologies, but a crucial limit for applications is their progressive aging over time, which dramatically affects their functionalities. The generally accepted paradigm is that such aging is gradual and its origin is in slower than exponential microscopic dynamics, akin to the ones in supercooled liquids or glasses. Nevertheless, time- and space-resolved measurements have provided contrasting evidence: dynamics faster than exponential, intermittency and abrupt structural changes. Here we use 3D computer simulations of a microscopic model to reveal that the timescales governing stress relaxation, respectively, through thermal fluctuations and elastic recovery are key for the aging dynamics. When thermal fluctuations are too weak, stress heterogeneities frozen-in upon solidification can still partially relax through elastically driven fluctuations. Such fluctuations are intermittent, because of strong correlations that persist over the timescale of experiments or simulations, leading to faster than exponential dynamics. Nature Publishing Group 2017-06-21 /pmc/articles/PMC5482056/ /pubmed/28635964 http://dx.doi.org/10.1038/ncomms15846 Text en Copyright © 2017, The Author(s) http://creativecommons.org/licenses/by/4.0/ Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Article Bouzid, Mehdi Colombo, Jader Barbosa, Lucas Vieira Del Gado, Emanuela Elastically driven intermittent microscopic dynamics in soft solids |
title | Elastically driven intermittent microscopic dynamics in soft solids |
title_full | Elastically driven intermittent microscopic dynamics in soft solids |
title_fullStr | Elastically driven intermittent microscopic dynamics in soft solids |
title_full_unstemmed | Elastically driven intermittent microscopic dynamics in soft solids |
title_short | Elastically driven intermittent microscopic dynamics in soft solids |
title_sort | elastically driven intermittent microscopic dynamics in soft solids |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5482056/ https://www.ncbi.nlm.nih.gov/pubmed/28635964 http://dx.doi.org/10.1038/ncomms15846 |
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